Grafting of oxo-vanadium Schiff base on graphene nanosheets and its catalytic activity for the oxidation of alcohols

2012 ◽  
Vol 22 (12) ◽  
pp. 5427 ◽  
Author(s):  
Harshal P. Mungse ◽  
Sanny Verma ◽  
Neeraj Kumar ◽  
Bir Sain ◽  
Om P. Khatri
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Graphene Nanosheets ◽  
Oxidation Of Alcohols

Synthesis, characterization, reactivity and catalytic activity of a novel chiral manganese Schiff base complex

2015 ◽  
Vol 39 (8) ◽  
pp. 6459-6464 ◽  
Author(s):  
Reza Azadbakht ◽  
Abbas Amini Manesh ◽  
Mahdieh Malayeri ◽  
Behzad Dehghani
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Carbonyl Compounds ◽  
Schiff Base Complex ◽  
Base Complex ◽  
Oxidation Of Alcohols ◽  
New Type

A new type of manganese-Schiff base complex was synthesized and used as a catalyst for the oxidation of alcohols to the carbonyl compounds.

Mono-, tri- and polynuclear copper(ii) complexes of Schiff-base ligands: synthesis, characterization and catalytic activity towards alcohol oxidation

2017 ◽  
Vol 41 (13) ◽  
pp. 5696-5706 ◽  
Author(s):  
Aradhita Bhattacharjee ◽  
Shibashis Halder ◽  
Koushik Ghosh ◽  
Corrado Rizzoli ◽  
Partha Roy
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Alcohol Oxidation ◽  
Polynuclear Complex ◽  
Schiff Base Ligands ◽  
Oxidation Of Alcohols

A mononuclear copper(ii) complex acts as a superior catalyst compared to a tri- or polynuclear complex towards oxidation of alcohols to the corresponding aldehydes.

Synthesis, structural characterization and catalytic activity of chlororuthenium(II) complexes with substituted Schiff base/phosphine ancillary ligands

2020 ◽  
Vol 75 (9-10) ◽  
pp. 851-857
Author(s):  
Chong Chen ◽  
Fule Wu ◽  
Jiao Ji ◽  
Ai-Quan Jia ◽  
Qian-Feng Zhang
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Structural Characterization ◽  
Room Temperature ◽  
Molecular Structures ◽  
Cationic Complex ◽  
Neutral Complex ◽  
Ancillary Ligands ◽  
X Ray ◽  
X Ray Crystallography

AbstractTreatment of [(η6-p-cymene)RuCl2]2 with one equivalent of chlorodiphenylphosphine in tetrahydrofuran at reflux afforded a neutral complex [(η6-p-cymene)RuCl2(κ1-P-PPh2OH)] (1). Similarly, the reaction of [Ru(bpy)2Cl2·2H2O] (bpy = 2,2′-bipyridine) and chlorodiphenylphosphine in methanol gave a cationic complex [Ru(bpy)2Cl(κ1-P-PPh2OCH3)](PF6) (2), while treatment of [RuCl2(PPh3)3] with [2-(C5H4N)CH=N(CH2)2N(CH3)2] (L1) in tetrahydrofuran at room temperature afforded a ruthenium(II) complex [Ru(PPh3)Cl2(κ3-N,N,N-L1)] (3). Interaction of the chloro-bridged complex [Ru(CO)2Cl2]n with one equivalent of [Ph2P(o-C6H4)CH=N(CH2)2N(CH3)2] (L2) led to the isolation of [Ru(CO)Cl2(κ3-P,N,N-L2)] (4). The molecular structures of the ruthenium(II) complexes 1–4 have been determined by single-crystal X-ray crystallography. The properties of the ruthenium(II) complex 4 as a hydrogenation catalyst for acetophenone were also tested.

Ferrocene-based porous organic polymer derived high-performance electrocatalysts for oxygen reduction

2017 ◽  
Vol 5 (42) ◽  
pp. 22163-22169 ◽  
Author(s):  
Baolong Zhou ◽  
Liangzhen Liu ◽  
Pingwei Cai ◽  
Guang Zeng ◽  
Xiaoqiang Li ◽  
...  
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Porous Carbon ◽  
High Performance ◽  
Reduction Reaction ◽  
Organic Polymer ◽  
Porous Organic Polymers ◽  
Porous Organic Polymer

Two nitrogen-rich porous organic polymers (POPs) were prepared via Schiff base chemistry. Carbonization of these POPs results in porous carbon nanohybrids which exhibit excellent catalytic activity toward the oxygen reduction reaction (ORR).

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