Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl3) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling of secondary and primary alcohols to give β-alkylated secondary alcohols. This catalyst demonstrated excellent durability during successive recycling without leaching of Ru which is ascribed to the strong binding of the pincer ligands to the metal ions.
A porous organic polymer (POP-POPh3) was readily prepared by oxidation of POP-PPh3 with H2O2. After coordination with PdCl2 and co-catalyst of CuBr2 precursor, a Pd/Cu bimetals-loaded porous organic polymer (Pd/Cu@POP-POPh3)...
In this study, a novel porphyrin-based porous organic polymer (POP) was constructed using 5,10,15,20-tetramine (4-aminophenyl) porphyrin (TAPP) and 5,5′-diformyl-2,2′-bipyridine (DPDD) as organic ligands via solvothermal method (represented as TAPP-DPDD-POP). Then,...