Synthesis and characterization of N-substituted poly(ethylenepyrrole): functionalization of ethylene–carbon monoxide alternating copolymers

Author(s):  
Jwu-Ting Chen ◽  
Yu-Sung Yeh ◽  
Ayusman Sen
1996 ◽  
Vol 32 (11) ◽  
pp. 1285-1288 ◽  
Author(s):  
Shui-Yu Lu ◽  
R.Michael Paton ◽  
Michael J. Green ◽  
Andrew R. Lucy

2006 ◽  
Vol 156 (7-8) ◽  
pp. 529-536 ◽  
Author(s):  
Laura O. Péres ◽  
Mauro R. Fernandes ◽  
Jarem R. Garcia ◽  
Shu Hui Wang ◽  
Francisco C. Nart

2002 ◽  
Vol 35 (9) ◽  
pp. 3474-3483 ◽  
Author(s):  
Jianfu Ding ◽  
Michael Day ◽  
Gilles Robertson ◽  
Jacques Roovers

1986 ◽  
Vol 64 (4) ◽  
pp. 751-759 ◽  
Author(s):  
Daniel Cozak ◽  
Abdelhakim Mardhy ◽  
André Morneau

The reaction of CpTi(CO)2 (1), Cp2TiCl (2), and Cp2TiCl2 (3) (Cp = η5-C5H5) with purine (PuH) and adenine (AdH) in organic solvents is described. The compound 1 reacts with both molecules in an oxidative fashion giving Cp2Ti(C5H3N4)(C5H4N4) (4) and (Cp2Ti)2(C5H3N5) (5) with concomitant liberation of molecular carbon monoxide and hydrogen (4:1) following a first order rate law in metal complex. The compound 2 forms an adduct compound Cp2TiCl(C5H4N4) (6) with PuH. Monosubstituted derivatives Cp2TiCl(C5H3N4) (7) and Cp2TiCl(C5H4N5) (8) are formed from the reaction of the deprotonated bases with 3. In addition to the usual elemental analysis, the characteristic ir, 1H nmr, epr, and ms results are given for the new compounds.


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