Synthesis and characterization of nanocrystalline copper–chromium catalyst and its application in the oxidation of carbon monoxide

2017 ◽  
Vol 107 ◽  
pp. 181-189 ◽  
Author(s):  
Sajad Mobini ◽  
Fereshteh Meshkani ◽  
Mehran Rezaei
Keyword(s):  
Carbon Monoxide ◽  
Synthesis And Characterization ◽  
Nanocrystalline Copper ◽  
Chromium Catalyst ◽  
Copper Chromium ◽  
Oxidation Of Carbon Monoxide

Synthesis and characterization of polyketoximes derived from alkene-carbon monoxide copolymers

1996 ◽  
Vol 32 (11) ◽  
pp. 1285-1288 ◽  
Author(s):  
Shui-Yu Lu ◽  
R.Michael Paton ◽  
Michael J. Green ◽  
Andrew R. Lucy
Keyword(s):  
Carbon Monoxide ◽  
Synthesis And Characterization

Titanocene derivatives of purine and adenine. Synthesis and characterization of reaction products with (η5-C5H5)2Ti(CO)2, (η5-C5H5)2TiCl, and (η5-C5H5)2TiCl2

1986 ◽  
Vol 64 (4) ◽  
pp. 751-759 ◽  
Author(s):  
Daniel Cozak ◽  
Abdelhakim Mardhy ◽  
André Morneau
Keyword(s):  
Carbon Monoxide ◽  
Metal Complex ◽  
Elemental Analysis ◽  
Synthesis And Characterization ◽  
Reaction Products ◽  
First Order ◽  
H Nmr ◽  
New Compounds ◽  
Derivatives Of

The reaction of CpTi(CO)2 (1), Cp2TiCl (2), and Cp2TiCl2 (3) (Cp = η5-C5H5) with purine (PuH) and adenine (AdH) in organic solvents is described. The compound 1 reacts with both molecules in an oxidative fashion giving Cp2Ti(C5H3N4)(C5H4N4) (4) and (Cp2Ti)2(C5H3N5) (5) with concomitant liberation of molecular carbon monoxide and hydrogen (4:1) following a first order rate law in metal complex. The compound 2 forms an adduct compound Cp2TiCl(C5H4N4) (6) with PuH. Monosubstituted derivatives Cp2TiCl(C5H3N4) (7) and Cp2TiCl(C5H4N5) (8) are formed from the reaction of the deprotonated bases with 3. In addition to the usual elemental analysis, the characteristic ir, 1H nmr, epr, and ms results are given for the new compounds.

Sign in / Sign up

Export Citation Format

Share Document