Aqueous-phase hydrogenation and hydrodeoxygenation of biomass-derived oxygenates with bimetallic catalysts

2014 ◽  
Vol 16 (2) ◽  
pp. 708 ◽  
Author(s):  
Jechan Lee ◽  
Yong Tae Kim ◽  
George W. Huber
2010 ◽  
Vol 53 (15-18) ◽  
pp. 1270-1273 ◽  
Author(s):  
Doan Pham Minh ◽  
Michèle Besson ◽  
Catherine Pinel ◽  
Patrick Fuertes ◽  
Carole Petitjean

2012 ◽  
Vol 65 (4) ◽  
pp. 653-660 ◽  
Author(s):  
C. B. Molina ◽  
A. H. Pizarro ◽  
J. A. Casas ◽  
J. J. Rodriguez

Bimetallic Pd–Rh catalysts supported on pillared clays have been prepared and tested for aqueous-phase hydrodechlorination (HDC) using 4-chlorophenol (4-CP) as target compound. These bimetallic catalysts combine the higher activity of Rh with the better stability of Pd found in previous works with monometallic catalysts. Different combinations of Pd and Rh amounting to 1 wt% total metal load were tested and the catalyst with 0.75 wt% Pd and 0.25 wt% Rh yielded the best results. Ecotoxicity and biodegradability (measured as BOD5/COD ratio) of the effluents were checked. A significant decrease of ecotoxicity was observed while biodegradability was dramatically improved from 0.02 for the initial 4-CP solution up to values higher than 0.6.


2006 ◽  
Vol 62 (3-4) ◽  
pp. 226-235 ◽  
Author(s):  
George W. Huber ◽  
John W. Shabaker ◽  
Steven T. Evans ◽  
James A. Dumesic

2019 ◽  
Vol 477 ◽  
pp. 110546 ◽  
Author(s):  
Yan Cheng ◽  
Hien Pham ◽  
Jiajie Huo ◽  
Robert Johnson ◽  
Abhaya K. Datye ◽  
...  

2012 ◽  
Vol 185 (1) ◽  
pp. 73-80 ◽  
Author(s):  
Ho-Dong Kim ◽  
Hyun Ju Park ◽  
Tae-Wan Kim ◽  
Kwang-Eun Jeong ◽  
Ho-Jeong Chae ◽  
...  

Langmuir ◽  
2018 ◽  
Vol 34 (4) ◽  
pp. 1300-1310 ◽  
Author(s):  
Madhulika Gupta ◽  
Tuhin S. Khan ◽  
Manish Agarwal ◽  
M. Ali Haider

RSC Advances ◽  
2017 ◽  
Vol 7 (64) ◽  
pp. 40437-40443 ◽  
Author(s):  
Xu Fang ◽  
Deren Fang

The influence of Sn on the activity and selectivity of Pd catalysts for the hydrodechlorination (HDC) of 4-chlorophenol (CP) in an aqueous phase was studied.


2021 ◽  
Vol 45 (14) ◽  
pp. 6512-6520
Author(s):  
Wanderson Ferraz do Valle ◽  
André Von-Held Soares ◽  
Yutao Xing ◽  
Fabio Barboza Passos

This work studied platinum and indium supported on alumina and silica as monometallic and bimetallic catalysts for the aqueous phase hydrogenolysis of glycerol towards 1,2-propanediol (1,2-PDO).


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