Total syntheses of (±)-musellarins A–C
The first, diastereoselective total syntheses of musellarins A–C were achieved concisely with 7.8–9.8% yields in 15–16 steps, featuring (i) Achmatowicz rearrangement, Kishi reduction, and Friedel–Crafts cyclization to construct the tricyclic framework and (ii) Heck coupling of aryldiazonium salts to introduce the aryl group into the dihydropyran in a 2,6-trans fashion.
2013 ◽
Vol 17
(19)
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pp. 2192-2224
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2014 ◽
Vol 11
(10)
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pp. 707-712
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2014 ◽
Vol 11
(6)
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pp. 787-823
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Keyword(s):
2005 ◽
Vol 70
(10)
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pp. 1696-1708
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Keyword(s):
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