A Ni(ii)-MOF: reversible guest adsorption and heterogeneous catalytic properties for silylcyanation of aromatic aldehydes

2015 ◽  
Vol 51 (5) ◽  
pp. 839-842 ◽  
Author(s):  
Xiao-Meng Zhang ◽  
Chao-Wei Zhao ◽  
Jian-Ping Ma ◽  
Yang Yu ◽  
Qi-Kui Liu ◽  
...  

A I2⊂Ni(ii)-MOF can be used as a highly active heterogeneous catalyst to promote solvent-free silylcyanation of aromatic aldehydes under mild conditions.

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.


2019 ◽  
Vol 7 (19) ◽  
pp. 11934-11943 ◽  
Author(s):  
Marvin Siebels ◽  
Carsten Schlüsener ◽  
Jörg Thomas ◽  
Yu-Xuan Xiao ◽  
Xiao-Yu Yang ◽  
...  

Rh@CTF-1 nanomaterial is a highly active (TOF ∼ 31 000 h−1) heterogeneous catalyst for the efficient hydrogenation of benzene under mild and solvent-free conditions.


2016 ◽  
Vol 45 (6) ◽  
pp. 2369-2373 ◽  
Author(s):  
Mei-Pin Liu ◽  
Yan-Ping Luo ◽  
Lei Xu ◽  
Lin Sun ◽  
Hong-Bin Du

Hollow-structured Si/SiC@C nanospheres, prepared through magnesiothermic reduction, exhibit excellent catalytic activities for chemical fixation of CO2 under mild, solvent-free conditions.


RSC Advances ◽  
2015 ◽  
Vol 5 (88) ◽  
pp. 72146-72149 ◽  
Author(s):  
Liangzhen Cai ◽  
Decai Meng ◽  
Shaoqi Zhan ◽  
Xiaoxia Yang ◽  
Taoping Liu ◽  
...  

A SO3H and NH2+ functional carbon-based solid acid was used as a highly active heterogeneous catalyst for the transesterification of various carboxylic methyl esters with alcohols under mild conditions.


2016 ◽  
Vol 52 (86) ◽  
pp. 12702-12705 ◽  
Author(s):  
Neng-Xiu Zhu ◽  
Chao-Wei Zhao ◽  
Jian-Cheng Wang ◽  
Yan-An Li ◽  
Yu-Bin Dong

I2@Cu4I4-MOF can be a highly heterogeneous catalyst to promote the tandem reaction of Friedel–Crafts alkylation of indoles with acetals under solvent-free conditions at room temperature.


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