scholarly journals A kinetico-mechanistic study on the C–H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexes

2014 ◽  
Vol 43 (36) ◽  
pp. 13525 ◽  
Author(s):  
Helena Font ◽  
Mercè Font-Bardia ◽  
Kerman Gómez ◽  
Gabriel González ◽  
Jaume Granell ◽  
...  
Keyword(s):  
Solid State ◽  
Bond Activation ◽  
Mechanistic Study ◽  
Dimeric Complexes

Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs

2008 ◽  
Vol 120 (13) ◽  
pp. 2469-2472 ◽  
Author(s):  
Tibor András Rokob ◽  
Andrea Hamza ◽  
András Stirling ◽  
Tibor Soós ◽  
Imre Pápai
Keyword(s):  
Bond Activation ◽  
Mechanistic Study ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

scholarly journals Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

2016 ◽  
Vol 52 (88) ◽  
pp. 12960-12963 ◽  
Author(s):  
Andrea Monas ◽  
Krunoslav Užarević ◽  
Ivan Halasz ◽  
Marina Juribašić Kulcsár ◽  
Manda Ćurić
Keyword(s):  
Methyl Orange ◽  
Solid State ◽  
Room Temperature ◽  
Bond Activation ◽  
Aqueous Media ◽  
Accelerated Aging ◽  
Water Soluble ◽  
Clean Synthesis

Room-temperature accelerated aging in the solid state has been applied for quantitative azobenzene C–H bond activation by Pd(OAc)2. Water-soluble dicyclopalladated methyl orange is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in aqueous media.

scholarly journals Shortwave infrared luminescent Pt-nanowires: a mechanistic study of emission in solution and in the solid state

2017 ◽  
Vol 46 (39) ◽  
pp. 13562-13581 ◽  
Author(s):  
Carl Cheadle ◽  
Jessica Ratcliff ◽  
Mikhail Berezin ◽  
Vadim Pal'shin ◽  
Victor N. Nemykin ◽  
...  
Keyword(s):  
Solid State ◽  
Mechanistic Study ◽  
Dark Green ◽  
Shortwave Infrared ◽  
Pt Nanowires

Yellow monomeric complexes of platinum with two cyanoxime ligands self-assemble into polymeric dark-green [PtL2]n1D stacks held by metallophillic interactions.

Development and Mechanistic Study of Quinoline-Directed Acyl C–O Bond Activation and Alkene Oxyacylation Reactions

2017 ◽  
Vol 82 (6) ◽  
pp. 2972-2983 ◽  
Author(s):  
Giang T. Hoang ◽  
Dylan J. Walsh ◽  
Kathryn A. McGarry ◽  
Constance B. Anderson ◽  
Christopher J. Douglas
Keyword(s):  
Bond Activation ◽  
Mechanistic Study
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