Selective carbon dioxide adsorption by mixed-ligand porous coordination polymers

CrystEngComm ◽  
2015 ◽  
Vol 17 (44) ◽  
pp. 8388-8413 ◽  
Author(s):  
Biswajit Bhattacharya ◽  
Debajyoti Ghoshal
Keyword(s):  
Carbon Dioxide ◽  
Solid State ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Mixed Ligand ◽  
Carbon Dioxide Adsorption ◽  
Porous Coordination Polymers ◽  
Metal Organic ◽  
Proper Design

Mixed ligand metal–organic frameworks (MOFs) have resolutely established themselves as a class of excellent solid state sorbents for carbon dioxide (CO2) and a proper design of such MOF can potentially improve not only the amount of CO2 adsorption, but also the selectivity of CO2 uptake over other gases and volatiles.

scholarly journals Carbon Dioxide Adsorption in Amine-Functionalized Mixed-Ligand Metal-Organic Frameworks of UiO-66 Topology

ChemSusChem ◽  
2014 ◽  
Vol 7 (12) ◽  
pp. 3382-3388 ◽  
Author(s):  
Jayashree Ethiraj ◽  
Elisa Albanese ◽  
Bartolomeo Civalleri ◽  
Jenny G. Vitillo ◽  
Francesca Bonino ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Mixed Ligand ◽  
Carbon Dioxide Adsorption ◽  
Amine Functionalized ◽  
Metal Organic

Efficient Solvent-Free Carbon Dioxide Fixation Reactions with Epoxides Under Mild Conditions by Mixed-Ligand Zinc(II) Metal-Organic Frameworks

ChemCatChem ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 2401-2408 ◽  
Author(s):  
Parth Patel ◽  
Bhavesh Parmar ◽  
Rukhsana I. Kureshy ◽  
Noor-ul Khan ◽  
Eringathodi Suresh
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Fixation ◽  
Mixed Ligand ◽  
Free Carbon ◽  
Solvent Free ◽  
Mild Conditions ◽  
Free Carbon Dioxide ◽  
Metal Organic

scholarly journals Poly(ionic liquid)-Modified Metal Organic Framework for Carbon Dioxide Adsorption

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 370 ◽  
Author(s):  
Guangyuan Yang ◽  
Jialin Yu ◽  
Sanwen Peng ◽  
Kuang Sheng ◽  
Haining Zhang
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Composite Materials ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Partial Pressure ◽  
Carbon Dioxide Adsorption ◽  
Solid Sorbent ◽  
Practical Applications ◽  
Metal Organic ◽  
Poly Ionic Liquid

The design and synthesis of solid sorbents for effective carbon dioxide adsorption are essential for practical applications regarding carbon emissions. Herein, we report the synthesis of composite materials consisting of amine-functionalized imidazolium-type poly(ionic liquid) (PIL) and metal organic frameworks (MOFs) through complexation of amino groups and metal ions. The carbon dioxide adsorption behavior of the synthesized composite materials was evaluated using the temperature-programmed desorption (TPD) technique. Benefiting from the large surface area of metal organic frameworks and high carbon dioxide diffusivity in ionic liquid moieties, the carbon dioxide adsorption capacity of the synthesized composite material reached 19.5 cm3·g−1, which is much higher than that of pristine metal organic frameworks (3.1 cm3·g−1) under carbon dioxide partial pressure of 0.2 bar at 25 °C. The results demonstrate that the combination of functionalized poly(ionic liquid) with metal organic frameworks can be a promising solid sorbent for carbon dioxide adsorption.

scholarly journals Cooperative Carbon Dioxide Adsorption in Alcoholamine‐ and Alkoxyalkylamine‐Functionalized Metal–Organic Frameworks

2020 ◽  
Vol 132 (44) ◽  
pp. 19636-19645
Author(s):  
Victor Y. Mao ◽  
Phillip J. Milner ◽  
Jung‐Hoon Lee ◽  
Alexander C. Forse ◽  
Eugene J. Kim ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Adsorption ◽  
Metal Organic

Selective gas adsorption in microporous metal–organic frameworks incorporating urotropine basic sites: an experimental and theoretical study

2015 ◽  
Vol 51 (73) ◽  
pp. 13918-13921 ◽  
Author(s):  
S. A. Sapchenko ◽  
D. N. Dybtsev ◽  
D. G. Samsonenko ◽  
R. V. Belosludov ◽  
V. R. Belosludov ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Ab Initio ◽  
Coordination Polymers ◽  
Theoretical Study ◽  
Gas Adsorption ◽  
Selective Adsorption ◽  
Metal Organic Frameworks ◽  
Porous Coordination Polymers ◽  
Basic Sites ◽  
Metal Organic

Urotropine-based porous coordination polymers with free N-donors demonstrate selective adsorption towards acidic gas substrates (C2H2 or CO2) as confirmed by isotherm measurements and ab initio DFT calculations.

Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks

2008 ◽  
Vol 130 (2) ◽  
pp. 406-407 ◽  
Author(s):  
Krista S. Walton ◽  
Andrew R. Millward ◽  
David Dubbeldam ◽  
Houston Frost ◽  
John J. Low ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Isotherms ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Adsorption ◽  
Metal Organic
Sign in / Sign up

Export Citation Format

Share Document