scholarly journals A detailed comparative structural study of the hydrogen bonded networks in solids, obtained by the reaction of 4,4′-bipyridine and varied alkane-α,ω-diphosphonic acids

CrystEngComm ◽  
2016 ◽  
Vol 18 (20) ◽  
pp. 3574-3584 ◽  
Author(s):  
M. van Megen ◽  
W. Frank ◽  
G. J. Reiss
2012 ◽  
Vol 68 (5) ◽  
pp. o188-o194 ◽  
Author(s):  
Andreas Lemmerer ◽  
Manuel A. Fernandes

Six ammonium carboxylate salts, namely cyclopentylammonium cinnamate, C5H12N+·C9H7O2−, (I), cyclohexylammonium cinnamate, C6H14N+·C9H7O2−, (II), cycloheptylammonium cinnamate form I, C7H16N+·C9H7O2−, (IIIa), and form II, (IIIb), cyclooctylammonium cinnamate, C8H18N+·C9H7O2−, (IV), and cyclododecylammonium cinnamate, C12H26N+·C9H7O2−, (V), are reported. Salts (II)–(V) all have a 1:1 ratio of cation to anion and feature three N+—H...O−hydrogen bonds forming one-dimensional hydrogen-bonded columns consisting of repeatingR43(10) rings, while salt (I) has a two-dimensional network made up of alternatingR44(12) andR68(20) rings. Salt (III) consists of two polymorphic forms,viz.form I havingZ′ = 1 and form II withZ′ = 2. The latter polymorph has disorder of the cycloheptane rings in the two cations, as well as whole-molecule disorder of one of the cinnamate anions. A similar, but ordered,Z′ = 2 structure is seen in salt (IV).


Author(s):  
Martin van Megen ◽  
Walter Frank ◽  
Guido J. Reiss

AbstractIn a comparative structural study, the solid state structures within the homologous series of alkane-


2004 ◽  
Vol 692 (1-3) ◽  
pp. 127-137 ◽  
Author(s):  
Nathalie Seurre ◽  
Katia Le Barbu-Debus ◽  
Françoise Lahmani ◽  
Anne Zehnacker-Rentien ◽  
Jerzy Sepiol

2003 ◽  
Vol 118 (20) ◽  
pp. 9157-9166 ◽  
Author(s):  
Christian Tanner ◽  
Debora Henseler ◽  
Samuel Leutwyler ◽  
Leslie L. Connell ◽  
Peter M. Felker

2018 ◽  
Vol 74 (9) ◽  
pp. 1276-1280
Author(s):  
Samuel C. Penner ◽  
Maryam Kalvandi ◽  
Jamie S. Ritch

Crystallographic studies of nitrogen-containing small molecules aid in the elucidation of their structure–activity relationships and modes of aggregation. In this study, two previously synthesized molecules are crystallographically characterized for the first time. Reaction of 2,4-dimethylaniline with N-bromosuccinimide affords the ortho-brominated derivative 2-bromo-4,6-dimethylaniline (1; C8H10BrN), which sublimates in vacuo to afford crystals featuring hydrogen-bonded chains as well as Type I halogen–halogen interactions. Conversely, alkylation of two equivalents of 2,4-dimethylaniline with 1,2-dibromoethane affords a separable mixture of N,N′-bis(2,4-dimethylphenyl)piperazine (2; C20H26N2), which was crystallographically characterized, as well as N,N′-bis(2,4-dimethylphenyl)ethylenediamine (3).


Author(s):  
James R. Gaylor ◽  
Fredda Schafer ◽  
Robert E. Nordquist

Several theories on the origin of the melanosome exist. These include the Golgi origin theory, in which a tyrosinase-rich protein is "packaged" by the Golgi apparatus, thus forming the early form of the melanosome. A second theory postulates a mitochondrial origin of melanosomes. Its author contends that the melanosome is a modified mitochondria which acquires melanin during its development. A third theory states that a pre-melanosome is formed in the smooth or rough endoplasmic reticulum. Protein aggregation is suggested by one author as a possible source of the melanosome. This fourth theory postulates that the melanosome originates when the protein products of several genetic loci aggregate in the cytoplasm of the melanocyte. It is this protein matrix on which the melanin is deposited. It was with these theories in mind that this project was undertaken.


1997 ◽  
Vol 222 (1-2) ◽  
pp. 131-136
Author(s):  
K Muruganandam
Keyword(s):  

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