scholarly journals The low frequency modes of solvated ions and ion pairs in aqueous electrolyte solutions: iron(ii) and iron(iii) chloride

2015 ◽  
Vol 17 (29) ◽  
pp. 19582-19591 ◽  
Author(s):  
Fabian Böhm ◽  
Vinay Sharma ◽  
Gerhard Schwaab ◽  
Martina Havenith
Keyword(s):  
Aqueous Electrolyte ◽  
Ion Pairs ◽  
Low Frequency ◽  
Electrolyte Solutions ◽  
Complex Species ◽  
Aqueous Electrolyte Solutions ◽  
Mixed Solutions ◽  
Solvated Ions ◽  
Fir Spectra

THz/FIR spectra of aqueous FeCl2 and FeCl3 solutions have been dissected into the contributions of different complex species, which were then used to identify the composition of unknown mixed solutions.

Promoting Nitrogen Electroreduction to Ammonia with Bismuth Nanocrystals and Potassium Cations in Water

2020 ◽  
Author(s):  
Jaecheol Choi ◽  
Hoang-Long Du ◽  
Manjunath Chatti ◽  
Bryan H. R. Suryanto ◽  
Alexandr Simonov ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Aqueous Electrolyte Solutions

We demonstrate that bismuth exhibits no measurable electrocatalytic activity for the nitrogen reduction reaction to ammonia in aqueous electrolyte solutions, contrary to several recent reports on the highly impressive rates of Bi-catalysed electrosynthesis of NH<sub>3</sub> from N<sub>2</sub>.

scholarly journals Macroscopic conductivity of aqueous electrolyte solutions scales with ultrafast microscopic ion motions

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Vasileios Balos ◽  
Sho Imoto ◽  
Roland R. Netz ◽  
Mischa Bonn ◽  
Douwe Jan Bonthuis ◽  
...  
Keyword(s):  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Aqueous Electrolyte Solutions

NMR Studies of Aqueous Electrolyte Solutions. IV. Hydration Numbers of Strong Electrolytes Determined from Temperature Effects on Proton Shifts

1971 ◽  
Vol 54 (1) ◽  
pp. 178-181 ◽  
Author(s):  
Brother Ferdinand J. Vogrin ◽  
Paul S. Knapp ◽  
William L. Flint ◽  
Arthur Anton ◽  
Gerald Highberger ◽  
...  
Keyword(s):  
Temperature Effects ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Hydration Numbers ◽  
Nmr Studies ◽  
Aqueous Electrolyte Solutions ◽  
Strong Electrolytes
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