The magnetocaloric effect with critical behavior of a periodic Anderson-like organic polymer

2016 ◽  
Vol 18 (1) ◽  
pp. 510-518 ◽  
Author(s):  
L. J. Ding ◽  
Y. Zhong ◽  
S. W. Fan ◽  
L. Y. Zhu

The magnetic entropy change (−ΔS) shows a double-peak structure, indicating a double magnetic cooling process via demagnetization.

2011 ◽  
Vol 98 (7) ◽  
pp. 072508 ◽  
Author(s):  
Jiyu Fan ◽  
Li Pi ◽  
Lei Zhang ◽  
Wei Tong ◽  
Langsheng Ling ◽  
...  

2013 ◽  
Vol 113 (9) ◽  
pp. 093902 ◽  
Author(s):  
J. C. Debnath ◽  
P. Shamba ◽  
A. M. Strydom ◽  
J. L. Wang ◽  
S. X. Dou

2021 ◽  
Author(s):  
Li Liningfang ◽  
Ximing Luo ◽  
Jia Wang ◽  
Jilei Wang ◽  
You Song ◽  
...  

Abstract The synthesis of large nano-sized cluster-molecules is a goal that synthesists and structural scientists have been pursuing, as well as a huge challenge. Herein, the largest 3d-4f metal clusters Cl12@Gd158Co38 and Br12@Gd158Co38 until now are obtained through the “multi-anions-template” strategy, with a protein-sized metal frame (ca. 4.3 × 3.6 × 3.5 nm3). Different from the mixed distribution of 3d and 4f metals and the hollow structure in the previous giant 3d-4f clusters, for the dense core-shell structure Cl12@Gd158Co38 and Br12@Gd158Co38, the Ln158 core with the highest Ln nuclearity number is induced by icosahedra-shaped templates [Cl12]12- or [Br12]12-, while 3d metals (Co) are distributed on its periphery. Their appearances point out a new structure type of non-open giant Ln-based clusters (metal number > 100) and provide an ideal model for studying the multi-level assembly of complex macromolecules. Additionally, Cl12@Gd158Co38 shows the largest magnetic entropy change (-∆Smmax = 46.95 J kg-1 K-1 under 2.0 K and ΔH = 7 T) among reported high-nuclearity 3d-4f clusters.


2016 ◽  
Vol 42 (1) ◽  
pp. 1036-1043 ◽  
Author(s):  
N. Mtiraoui ◽  
M. Chennabasappa ◽  
R. Decourt ◽  
O. Toulemonde ◽  
J. Dhahri ◽  
...  

2012 ◽  
Vol 324 (22) ◽  
pp. 3615-3619 ◽  
Author(s):  
Sonia Ben Abdelkhalek ◽  
Nabil Kallel ◽  
Sami Kallel ◽  
Octavio Peña ◽  
Mohamed Oumezzine

2019 ◽  
Vol 195 (1-2) ◽  
pp. 81-95
Author(s):  
Jiao Liu ◽  
Wen-qing Wang ◽  
Hong-ye Wu ◽  
Ting Wang ◽  
Ye Tian ◽  
...  

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