Encapsulation of dyes in metal–organic frameworks and their tunable nonlinear optical properties

Two series of cationic dyes have been encapsulated in the 1D channel of MOFs, and the tunable second order nonlinear optical properties of these MOF⊃dye materials were observed.

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Understanding the Linear and Second-Order Nonlinear Optical Properties of UiO-66-Derived Metal–Organic Frameworks: A Comprehensive DFT Study

The Journal of Physical Chemistry C ◽

10.1021/acs.jpcc.0c01580 ◽

2020 ◽

Vol 124 (21) ◽

pp. 11595-11608

Author(s):

Bilian Ni ◽

Weiming Sun ◽

Jie Kang ◽

Yongfan Zhang

Keyword(s):

Optical Properties ◽

Nonlinear Optical ◽

Metal Organic Frameworks ◽

Second Order ◽

Nonlinear Optical Properties ◽

Dft Study ◽

Metal Organic

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Nonlinear optical properties, upconversion and lasing in metal–organic frameworks

Chemical Society Reviews ◽

10.1039/c7cs00162b ◽

2017 ◽

Vol 46 (16) ◽

pp. 4976-5004 ◽

Cited By ~ 227

Author(s):

Raghavender Medishetty ◽

Jan K. Zaręba ◽

David Mayer ◽

Marek Samoć ◽

Roland A. Fischer

Keyword(s):

Optical Properties ◽

Coordination Polymers ◽

Building Block ◽

Nonlinear Optical ◽

Metal Organic Frameworks ◽

Nonlinear Optical Properties ◽

Modular Approach ◽

Vast Array ◽

Metal Organic

The building block modular approach that lies behind coordination polymers (CPs) and metal–organic frameworks (MOFs) results not only in a plethora of materials that can be obtained but also in a vast array of nonlinear optical properties that could be aimed at.

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Crystal structure or chemical composition of salt–sugar-based metal–organic frameworks: what are the nonlinear optical properties due to?

Acta Crystallographica Section B Structural Science Crystal Engineering and Materials ◽

10.1107/s2052520621004637 ◽

2021 ◽

Vol 77 (4) ◽

Author(s):

Domenica Marabello ◽

Paola Antoniotti ◽

Paola Benzi ◽

Fabio Beccari ◽

Carlo Canepa ◽

...

Keyword(s):

Optical Properties ◽

Crystal Engineering ◽

Density Functional ◽

Nonlinear Optical ◽

Second Harmonic ◽

Imaging Techniques ◽

Metal Organic Frameworks ◽

Nonlinear Optical Properties ◽

Crystal Density ◽

Metal Organic

In the last few decades optical imaging techniques based on nonlinear optical properties have been of interest for biosensing applications. This work focuses on two isostructural and isomorphous sugar-derived metal–organic frameworks (MOFs) with second-harmonic generation (SHG) properties, in order to investigate their possible application as biosensors in view of their high biocompatibility. Combining 2-deoxy-D-galactose with the metal halogenides CaX 2 (X = Br, I), two new isomorphous MOFs of formula [Ca(C6H12O5)2]X 2 were obtained and characterized through single-crystal X-ray diffraction. The first-order static hyperpolarizability and second-order susceptibility were estimated by in vacuo and in-crystal density functional theory calculations, and compared with the experimental SHG response of powdered samples. The parameters influencing the SHG response of these compounds were investigated by comparison with similar previously analysed MOFs, to understand how to design more efficient materials to be used as nanoprobes by exploiting crystal engineering techniques.

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Second-order nonlinear optical properties of two chalcone derivatives: insights from sum-over-states

Physical Chemistry Chemical Physics ◽

10.1039/d0cp06469f ◽

2021 ◽

Author(s):

Jean Custodio ◽

Giulio Demetrius Creazo d'Oliveira ◽

Fernando Gotardo ◽

Leandro Cocca ◽

Leonardo De Boni ◽

...

Keyword(s):

Optical Properties ◽

Nonlinear Optical ◽

Theoretical Study ◽

Second Order ◽

Nonlinear Optical Properties ◽

Chalcone Derivatives

In the following study, a combined experimental and theoretical study of the nonlinear optical properties (NLO) of two chalcone derivatives, (E)-3-(2-methoxyphenyl)-1-(2-(phenylsulfonylamine)phenyl)prop-2-en-1-one (MPSP) and (E)-3-(3-nitrophenyl)-1-(2-(phenylsulfonylamine)phenyl)prop-2-en-1-one (NPSP) in DMSO is reported. Single...

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