Analytical spectral dependent partial least squares regression: a study of nuclear waste glass from thorium based fuel using LIBS

2015 ◽  
Vol 30 (12) ◽  
pp. 2507-2515 ◽  
Author(s):  
Manjeet Singh ◽  
Vijay Karki ◽  
Raman K. Mishra ◽  
Amar Kumar ◽  
C. P. Kaushik ◽  
...  

LIBS (Laser Induced Breakdown Spectroscopy) for simultaneous multielement quantification of nuclear waste glass using a spectral modification based PLSR approach.

2020 ◽  
Vol 35 (7) ◽  
pp. 1498-1498
Author(s):  
Zhihao Zhu ◽  
Jiaming Li ◽  
Yangmin Guo ◽  
Xiao Cheng ◽  
Yun Tang ◽  
...  

Correction for ‘Accuracy improvement of boron by molecular emission with a genetic algorithm and partial least squares regression model in laser-induced breakdown spectroscopy’ by Zhihao Zhu et al., J. Anal. At. Spectrom., 2018, 33, 205–209, DOI: 10.1039/C7JA00356K.


Molecules ◽  
2018 ◽  
Vol 23 (10) ◽  
pp. 2492 ◽  
Author(s):  
Xiaodan Liu ◽  
Fei Liu ◽  
Weihao Huang ◽  
Jiyu Peng ◽  
Tingting Shen ◽  
...  

Rapid detection of Cd content in soil is beneficial to the prevention of soil heavy metal pollution. In this study, we aimed at exploring the rapid quantitative detection ability of laser- induced breakdown spectroscopy (LIBS) under the conditions of air and Ar for Cd in soil, and finding a fast and accurate method for quantitative detection of heavy metal elements in soil. Spectral intensity of Cd and system performance under air and Ar conditions were analyzed and compared. The univariate model and multivariate models of partial least-squares regression (PLSR) and least-squares support vector machine (LS-SVM) of Cd under the air and Ar conditions were built, and the LS-SVM model under the Ar condition obtained the best performance. In addition, the principle of influence of Ar on LIBS detection was investigated by analyzing the three-dimensional profile of the ablation crater. The overall results indicated that LIBS combined with LS-SVM under the Ar condition could be a useful tool for the accurate quantitative detection of Cd in soil and could provide reference for environmental monitoring.


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