A variety of metal–organic and supramolecular networks constructed from a new flexible multifunctional building block bearing picolinate and terephthalate functionalities: hydrothermal self-assembly, structural features, magnetic and luminescent properties

RSC Advances ◽  
2015 ◽  
Vol 5 (106) ◽  
pp. 87484-87495 ◽  
Author(s):  
Yong-Liang Shao ◽  
Yan-Hui Cui ◽  
Jin-Zhong Gu ◽  
Alexander M. Kirillov ◽  
Jiang Wu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Building Block ◽  
Coordination Compounds ◽  
Luminescent Properties ◽  
Structural Features ◽  
Metal Organic ◽  
Supramolecular Networks

A novel multifunctional building block was designed and applied for the synthesis of diverse coordination compounds.

Exploring biphenyl-2,4,4′-tricarboxylic acid as a flexible building block for the hydrothermal self-assembly of diverse metal–organic and supramolecular networks

CrystEngComm ◽  
2016 ◽  
Vol 18 (5) ◽  
pp. 765-778 ◽  
Author(s):  
Yong-Liang Shao ◽  
Yan-Hui Cui ◽  
Jin-Zhong Gu ◽  
Jiang Wu ◽  
Ya-Wen Wang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Magnetic Properties ◽  
Self Assembly ◽  
Building Block ◽  
Coordination Compounds ◽  
Tricarboxylic Acid ◽  
Topological Features ◽  
Metal Organic ◽  
Supramolecular Networks

This contribution reports the hydrothermal self-assembly synthesis, characterization, thermal stability, structural and topological features, and luminescence or magnetic properties of a new series of nine coordination compounds.

A new series of Co, Ni, Zn, and Cd metal–organic architectures driven by an unsymmetrical biphenyl-tricarboxylic acid: hydrothermal assembly, structural features and properties

2018 ◽  
Vol 47 (22) ◽  
pp. 7431-7444 ◽  
Author(s):  
Jin-Zhong Gu ◽  
Yan Cai ◽  
Zi-Yue Qian ◽  
Min Wen ◽  
Zi-Fa Shi ◽  
...  
Keyword(s):  
Building Block ◽  
Coordination Compounds ◽  
Structural Features ◽  
Tricarboxylic Acid ◽  
Main Building ◽  
Metal Organic

Twelve new Zn(ii), Ni(ii), Co(ii), and Cd(ii) coordination compounds with diverse dimensionalities were assembled using 3′-nitro-biphenyl-2,4,4′-tricarboxylic acid as a main building block.

Exploring 4-(3-carboxyphenyl)picolinic acid as a semirigid building block for the hydrothermal self-assembly of diverse metal–organic and supramolecular networks

CrystEngComm ◽  
2017 ◽  
Vol 19 (1) ◽  
pp. 117-128 ◽  
Author(s):  
Jin-Zhong Gu ◽  
Xiao-Xiao Liang ◽  
Yan-Hui Cui ◽  
Jiang Wu ◽  
Alexander M. Kirillov
Keyword(s):  
Self Assembly ◽  
Building Block ◽  
Picolinic Acid ◽  
Metal Organic ◽  
Supramolecular Networks

H-Bonded and metal(ii)–organic architectures assembled from an unexplored aromatic tricarboxylic acid: structural variety and functional properties

2020 ◽  
Vol 49 (21) ◽  
pp. 7197-7209 ◽  
Author(s):  
Jin-Zhong Gu ◽  
Shi-Mao Wan ◽  
Marina V. Kirillova ◽  
Alexander M. Kirillov
Keyword(s):  
Nicotinic Acid ◽  
Functional Properties ◽  
Building Block ◽  
Coordination Compounds ◽  
Structural Features ◽  
Tricarboxylic Acid ◽  
Structural Variety

2,5-Di(4-carboxylphenyl)nicotinic acid was explored as a novel building block for assembling nine metal(ii) coordination compounds; these were fully characterized and their structural features and functional properties were investigated.

scholarly journals Inverse Design of Nanoporous Crystalline Reticular Materials with Deep Generative Models

2020 ◽  
Author(s):  
Zhenpeng Yao ◽  
Benjamin Sanchez-Lengeling ◽  
N. Scott Bobbitt ◽  
Benjamin J. Bucior ◽  
Sai Govind Hari Kumar ◽  
...  
Keyword(s):  
Self Assembly ◽  
Metal Organic Framework ◽  
Internal Surface ◽  
Building Blocks ◽  
Structural Features ◽  
Generative Models ◽  
Combinatorial Design ◽  
Surface Areas ◽  
Molecular Building Blocks ◽  
Metal Organic

Reticular frameworks are crystalline porous materials that form <i>via</i> the self-assembly of molecular building blocks (<i>i.e.</i>, nodes and linkers) in different topologies. Many of them have high internal surface areas and other desirable properties for gas storage, separation, and other applications. The notable variety of the possible building blocks and the diverse ways they can be assembled endow reticular frameworks with a near-infinite combinatorial design space, making reticular chemistry both promising and challenging for prospective materials design. Here, we propose an automated nanoporous materials discovery platform powered by a supramolecular variational autoencoder (SmVAE) for the generative design of reticular materials with desired functions. We demonstrate the automated design process with a class of metal-organic framework (MOF) structures and the goal of separating CO<sub>2</sub> from natural gas or flue gas. Our model exhibits high fidelity in capturing structural features and reconstructing MOF structures. We show that the autoencoder has a promising optimization capability when jointly trained with multiple top adsorbent candidates identified for superior gas separation. MOFs discovered here are strongly competitive against some of the best-performing MOFs/zeolites ever reported. This platform lays the groundwork for the design of reticular frameworks for desired applications.

scholarly journals Inverse Design of Nanoporous Crystalline Reticular Materials with Deep Generative Models

2020 ◽  
Author(s):  
Zhenpeng Yao ◽  
Benjamin Sanchez-Lengeling ◽  
N. Scott Bobbitt ◽  
Benjamin J. Bucior ◽  
Sai Govind Hari Kumar ◽  
...  
Keyword(s):  
Self Assembly ◽  
Metal Organic Framework ◽  
Internal Surface ◽  
Building Blocks ◽  
Structural Features ◽  
Generative Models ◽  
Combinatorial Design ◽  
Surface Areas ◽  
Molecular Building Blocks ◽  
Metal Organic

Reticular frameworks are crystalline porous materials that form <i>via</i> the self-assembly of molecular building blocks (<i>i.e.</i>, nodes and linkers) in different topologies. Many of them have high internal surface areas and other desirable properties for gas storage, separation, and other applications. The notable variety of the possible building blocks and the diverse ways they can be assembled endow reticular frameworks with a near-infinite combinatorial design space, making reticular chemistry both promising and challenging for prospective materials design. Here, we propose an automated nanoporous materials discovery platform powered by a supramolecular variational autoencoder (SmVAE) for the generative design of reticular materials with desired functions. We demonstrate the automated design process with a class of metal-organic framework (MOF) structures and the goal of separating CO<sub>2</sub> from natural gas or flue gas. Our model exhibits high fidelity in capturing structural features and reconstructing MOF structures. We show that the autoencoder has a promising optimization capability when jointly trained with multiple top adsorbent candidates identified for superior gas separation. MOFs discovered here are strongly competitive against some of the best-performing MOFs/zeolites ever reported. This platform lays the groundwork for the design of reticular frameworks for desired applications.

scholarly journals Self-Assembly of Catalytically Active Supramolecular Coordination Compounds within Metal–Organic Frameworks

2019 ◽  
Vol 141 (26) ◽  
pp. 10350-10360 ◽  
Author(s):  
Rosa Adam ◽  
Marta Mon ◽  
Rossella Greco ◽  
Lucas H. G. Kalinke ◽  
Alejandro Vidal-Moya ◽  
...  
Keyword(s):  
Self Assembly ◽  
Coordination Compounds ◽  
Metal Organic Frameworks ◽  
Supramolecular Coordination ◽  
Catalytically Active ◽  
Metal Organic

4,4′-(Pyridine-2,5-diyl)dibenzoic acid as a building block for Cd(II) and Mn(II) coordination compounds: Synthesis, structural features and properties

2015 ◽  
Vol 435 ◽  
pp. 60-65
Author(s):  
Yu Li ◽  
Qiang Zhou ◽  
Xun-Zhong Zou ◽  
Jin-Zhong Gu ◽  
Bo Chen ◽  
...  
Keyword(s):  
Building Block ◽  
Coordination Compounds ◽  
Structural Features
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