scholarly journals Self-Assembly of Catalytically Active Supramolecular Coordination Compounds within Metal–Organic Frameworks

2019 ◽  
Vol 141 (26) ◽  
pp. 10350-10360 ◽  
Author(s):  
Rosa Adam ◽  
Marta Mon ◽  
Rossella Greco ◽  
Lucas H. G. Kalinke ◽  
Alejandro Vidal-Moya ◽  
...  
Keyword(s):  
Self Assembly ◽  
Coordination Compounds ◽  
Metal Organic Frameworks ◽  
Supramolecular Coordination ◽  
Catalytically Active ◽  
Metal Organic

scholarly journals Mechanochemical and solvent-free assembly of zirconium-based metal–organic frameworks

2016 ◽  
Vol 52 (10) ◽  
pp. 2133-2136 ◽  
Author(s):  
Krunoslav Užarević ◽  
Timothy C. Wang ◽  
Su-Young Moon ◽  
Athena M. Fidelli ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Solid State ◽  
High Temperatures ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Accelerated Aging ◽  
Solvent Free ◽  
Catalytically Active ◽  
Metal Organic ◽  
Strong Acids ◽  
Zirconium Metal

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.

scholarly journals Effect of linker functionalisation on the catalytic properties of Cu nanoclusters embedded in MOFs in direct CO and CO2 reduction by H2

2021 ◽  
Author(s):  
Cornelia Elizabeth Pompe ◽  
Petra Agota Szilagyi
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Catalytically Active ◽  
Metal Organic ◽  
Cu Nanoclusters

Metal-organic frameworks are promising host supporting matrices for catalytically active guest. In particular, their crystallinity renders them desirable as their pores may act as atom-precise templates for the growth of...

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

A Molecular Artisans Guide to Supramolecular Coordination Complexes and Metal Organic Frameworks

2015 ◽  
Vol 03 (01n02) ◽  
pp. 1540004 ◽  
Author(s):  
Xialu Wu ◽  
David J. Young ◽  
T. S. Andy Hor
Keyword(s):  
Chemical Reactivity ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Coordination Complexes ◽  
Large Molecules ◽  
Molecular Building Blocks ◽  
Supramolecular Coordination ◽  
Metal Organic ◽  
Molecular Synthesis ◽  
And Function

As molecular synthesis advances, we are beginning to learn control of not only the chemical reactivity (and function) of molecules, but also of their interactions with other molecules. It is this basic idea that has led to the current explosion of supramolecular science and engineering. Parallel to this development, chemists have been actively pursuing the design of very large molecules using basic molecular building blocks. Herein, we review the general development of supramolecular chemistry and particularly of two new branches: supramolecular coordination complexes (SCCs) and metal organic frameworks (MOFs). These two fields are discussed in detail with typical examples to illustrate what is now possible and what challenges lie ahead for tomorrow's molecular artisans.

Recent advances in biomolecule immobilization based on self-assembly: organic–inorganic hybrid nanoflowers and metal–organic frameworks as novel substrates

2018 ◽  
Vol 6 (11) ◽  
pp. 1581-1594 ◽  
Author(s):  
Zhixian Lei ◽  
Chenling Gao ◽  
Lei Chen ◽  
Yanting He ◽  
Wende Ma ◽  
...  
Keyword(s):  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Inorganic Hybrid ◽  
The Past ◽  
Biomolecule Immobilization ◽  
Recent Advances ◽  
Metal Organic

In the past few years, the immobilization of biomolecules on hybrid nanoflowers and metal–organic frameworks (MOFs) via self-assembly synthesis has received much attention due to its superior advantages.

scholarly journals In situ self-assembly of zirconium metal–organic frameworks onto ultrathin carbon nitride for enhanced visible light-driven conversion of CO2 to CO

2020 ◽  
Vol 8 (12) ◽  
pp. 6034-6040 ◽  
Author(s):  
Yanan Wang ◽  
Wenlong Zhen ◽  
Yiqing Zeng ◽  
Shipeng Wan ◽  
Haiwei Guo ◽  
...  
Keyword(s):  
Visible Light ◽  
Self Assembly ◽  
Carbon Nitride ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Assembly Method ◽  
Visible Light Driven ◽  
Metal Organic ◽  
Zirconium Metal

A series of Zr-porphyrin metal–organic framework (Zr-PMOF)/ultrathin g-C3N4 (UCN) heterostructure photocatalysts, as stable and efficient catalysts for the photoreduction of CO2, have been fabricated via a facile in situ hydrothermal self-assembly method.

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