Washing pretreatment with light bio-oil and its effect on pyrolysis products of bio-oil and biochar

RSC Advances ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 5270-5277 ◽  
Author(s):  
Shuping Zhang ◽  
Yuanquan Xiong

This work demonstrates a new method where rice husk is converted into value added bio-based products, such as bio-oil and biochar, by washing pretreatment with light bio-oil followed by fast pyrolysis.

BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 7118-7126
Author(s):  
Carolina Kravetz ◽  
Carlos Leca ◽  
José Otávio Brito ◽  
Daniel Saloni ◽  
David C. Tilotta

Orange trees in Brazil are often burned as a means of eradication when they become infected with Huanglongbing disease. Rather than destroying them, which is a low-value proposition, one potential option is to utilize the biomass through pyrolysis. In this preliminary work, orange trees (Citrus sinensis) otherwise selected for purging, were sampled and pyrolyzed at 500 °C, and the charcoal and bio-oil were evaluated for potential value-added use. The results showed that the pyrolysis process resulted in 26.3% charcoal, 57.6% bio-oil, and 16.0% non-condensable gases. Qualitative analysis of the bio-oil by gas chromatography/mass spectrometry found 178 chemical compounds; however, only 25% of those compounds could be reliably identified. Potential applications of the compounds identified in the bio-oil were determined by examining the published literature, and it was found that at least 73% of them showed promise. Finally, initial studies on the immediate analysis of the pyrolysis charcoal showed that it potentially meets the standards set forth for Brazilian domestic use.


Energy ◽  
2019 ◽  
Vol 186 ◽  
pp. 115882 ◽  
Author(s):  
Wenfei Cai ◽  
Ning Kang ◽  
Moon Ki Jang ◽  
Chen Sun ◽  
Ronghou Liu ◽  
...  

Cellulose ◽  
2019 ◽  
Vol 26 (15) ◽  
pp. 8465-8474 ◽  
Author(s):  
Yuna Ma ◽  
Huiyan Zhang ◽  
Huaizhou Yang ◽  
Yaping Zhang

Author(s):  
Marcos Antônio KLUNK ◽  
Sudipta DASGUPTA ◽  
Mohuli DAS

Rice husk is among the products that stand out in use, and it is used as an alternative source of energy. The use of rice husk as biomass in the feeding of pyrolytic reactors for power generation and chemical products can reduce the environmental problem destination of this waste. The advantages of this process are in the proper disposal of this waste and energy generation. Fast pyrolysis of the rice husk was carried out in temperatures of 400-600°C. This work aims to evaluate the influence of temperature on yield and product composition of the gas, bio-oil, and char. The yield of bio-oil proved to be efficient (62 wt.% at 450°C) due to the high heat transfer and mass, as well as the residence time in the reactor. In addition, bio-oil production decreases slightly due to increased gas yield (1 to 15 wt.%) as the temperature increases in the range of 400-600°C, with the composition being severely affected, i.e., The concentration of CO increases and that of CO2 decreases. In addition, a slight increase in the concentration of CH4 and C2-C4 hydrocarbons occurs with increasing temperature. The yield of char at 400°C and 600°C was 41.14-34.77 wt.%, respectively, corresponding to a decrease of 16 wt.%. The char obtained is of low heating value but has good features for the production of active carbons and amorphous silica. These results demonstrate the efficiency and optimization of the fast pyrolysis of rice husk, in order to obtain biooil and char.


2017 ◽  
Vol 135 ◽  
pp. 226-238 ◽  
Author(s):  
Pedro José Sanches Filho ◽  
Lucas Aldrigui Silveira ◽  
Glauco Rasmussen Betemps ◽  
Gissele Oliveira Montenegro ◽  
Daniele Martin Sampaio ◽  
...  
Keyword(s):  

2011 ◽  
Vol 84 (2) ◽  
pp. 73-79 ◽  
Author(s):  
R H Liu ◽  
C J Shen ◽  
H J Wu ◽  
C J Deng ◽  
S Y Liu

2011 ◽  
Vol 25 (9) ◽  
pp. 4113-4121 ◽  
Author(s):  
Sirimirin Meesuk ◽  
Jing-Pei Cao ◽  
Kazuyoshi Sato ◽  
Yukiko Ogawa ◽  
Takayuki Takarada

2020 ◽  
Author(s):  
Zakari BOUBACAR LAOUGE ◽  
Hasan MERDUN

Abstract Fast pyrolysis is an attractive way of converting abundant biomass resources into valuable products such as bio-oil. Nevertheless, high oxygenated compounds and water content of bio-oil limit its direct use as fuel or chemicals. Catalytic fast pyrolysis (CFP) is able to improve bio-oil properties so that downstream upgrading processes can be economically feasible. In this study five different catalysts such as zeolite socony mobil-5 (ZSM-5), cerium dioxide (CeO2), zirconium dioxide (ZrO2), zinc oxide (ZnO), and sodium carbonate (Na2CO3) were employed due to their potential in enhancing bio-oil properties. CFP of pearl millet (PM) and Sida cordifolia (Sida) was performed to investigate the effects of catalysts on the products distribution and chemical contents of bio-oil. The results showed that bio-oil yield decreased during CFP regardless of catalyst and biomass types. Among all catalysts, CeO2 was found to be the most suitable to produce acids and alkanes from CFP of PM; and acids, ketones, and aromatics from CFP of Sida. The high production of ketones from PM and alkanes from Sida was observed with Na2CO3 catalyst. The ZrO2 catalyst indicated the high aromatics production from PM, whereas alcohols, amines, and others were abundant in bio-oil from CFP of PM using ZSM-5. Overall, PM and Sida can be used to produce fuel or value-added chemicals through CFP.


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