Application of the SARA method for determination of hydrocarbons by GC/qMS in bio-oil obtained by fast pyrolysis of rice husk

2017 ◽  
Vol 135 ◽  
pp. 226-238 ◽  
Author(s):  
Pedro José Sanches Filho ◽  
Lucas Aldrigui Silveira ◽  
Glauco Rasmussen Betemps ◽  
Gissele Oliveira Montenegro ◽  
Daniele Martin Sampaio ◽  
...  
Keyword(s):  
Energy ◽  
2019 ◽  
Vol 186 ◽  
pp. 115882 ◽  
Author(s):  
Wenfei Cai ◽  
Ning Kang ◽  
Moon Ki Jang ◽  
Chen Sun ◽  
Ronghou Liu ◽  
...  

Cellulose ◽  
2019 ◽  
Vol 26 (15) ◽  
pp. 8465-8474 ◽  
Author(s):  
Yuna Ma ◽  
Huiyan Zhang ◽  
Huaizhou Yang ◽  
Yaping Zhang

Author(s):  
Marcos Antônio KLUNK ◽  
Sudipta DASGUPTA ◽  
Mohuli DAS

Rice husk is among the products that stand out in use, and it is used as an alternative source of energy. The use of rice husk as biomass in the feeding of pyrolytic reactors for power generation and chemical products can reduce the environmental problem destination of this waste. The advantages of this process are in the proper disposal of this waste and energy generation. Fast pyrolysis of the rice husk was carried out in temperatures of 400-600°C. This work aims to evaluate the influence of temperature on yield and product composition of the gas, bio-oil, and char. The yield of bio-oil proved to be efficient (62 wt.% at 450°C) due to the high heat transfer and mass, as well as the residence time in the reactor. In addition, bio-oil production decreases slightly due to increased gas yield (1 to 15 wt.%) as the temperature increases in the range of 400-600°C, with the composition being severely affected, i.e., The concentration of CO increases and that of CO2 decreases. In addition, a slight increase in the concentration of CH4 and C2-C4 hydrocarbons occurs with increasing temperature. The yield of char at 400°C and 600°C was 41.14-34.77 wt.%, respectively, corresponding to a decrease of 16 wt.%. The char obtained is of low heating value but has good features for the production of active carbons and amorphous silica. These results demonstrate the efficiency and optimization of the fast pyrolysis of rice husk, in order to obtain biooil and char.


2011 ◽  
Vol 84 (2) ◽  
pp. 73-79 ◽  
Author(s):  
R H Liu ◽  
C J Shen ◽  
H J Wu ◽  
C J Deng ◽  
S Y Liu

2011 ◽  
Vol 25 (9) ◽  
pp. 4113-4121 ◽  
Author(s):  
Sirimirin Meesuk ◽  
Jing-Pei Cao ◽  
Kazuyoshi Sato ◽  
Yukiko Ogawa ◽  
Takayuki Takarada

2020 ◽  
Vol 39 (1) ◽  
pp. 65-77
Author(s):  
Jacek Grams

AbstractFast pyrolysis of lignocellulosic biomass is one of the most promising methods of the production of renewable fuels. However, an optimization of the conditions of bio-oil production is not possible without comprehensive analysis of the composition of formed products. There are several methods for the determination of distribution of products formed during thermal decomposition of biomass with chromatography being the most versatile among them. Although, due to the complex structure of bio-oil (presence of hundreds chemical compounds with different chemical character), an interpretation of the obtained chromatograms is not an easy task. Therefore, the aim of this work is to present an application of different chromatographic methods to the analysis of the composition of the mixture of products formed in high temperature decomposition of lignocellulosic feedstock. It includes pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), two dimensional gas (GC x GC) or liquid chromatography (LC x LC) and initial fractionation of bio-oil components. Moreover, the problems connected with the analysis of bio-oils formed with the use of various fast pyrolysis reactors and capabilities of multivariate analysis are discussed.


RSC Advances ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 5270-5277 ◽  
Author(s):  
Shuping Zhang ◽  
Yuanquan Xiong

This work demonstrates a new method where rice husk is converted into value added bio-based products, such as bio-oil and biochar, by washing pretreatment with light bio-oil followed by fast pyrolysis.


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