Integration of Si in a metal foam current collector for stable electrochemical cycling in Li-ion batteries

2015 ◽  
Vol 3 (18) ◽  
pp. 10114-10118 ◽  
Author(s):  
Chunsong Zhao ◽  
Shuwei Li ◽  
Xi Luo ◽  
Bo Li ◽  
Wei Pan ◽  
...  

We improve the electrochemical performance of Li-ion batteries by trapping micron-sized silicon particles inside a metal foam current collector in Li-ion batteries.

Author(s):  
Gui-Yang Luo ◽  
Yi-Jing Gu ◽  
Yuan Liu ◽  
Zi-Liang Chen ◽  
Yong-lin Huo ◽  
...  

2019 ◽  
Vol 7 (41) ◽  
pp. 23679-23726 ◽  
Author(s):  
Manoj K. Jangid ◽  
Amartya Mukhopadhyay

Monitoring stress development in electrodes in-situ provides a host of real-time information on electro-chemo-mechanical aspects as functions of SOC and electrochemical potential.


Materials ◽  
2018 ◽  
Vol 11 (6) ◽  
pp. 1018 ◽  
Author(s):  
Jin-Young So ◽  
Chan-Ho Lee ◽  
Ji-Eun Kim ◽  
Hyun-Jee Kim ◽  
Joonha Jun ◽  
...  

Author(s):  
Malcolm Stein ◽  
Chien-Fan Chen ◽  
Matthew Mullings ◽  
David Jaime ◽  
Audrey Zaleski ◽  
...  

Particle size plays an important role in the electrochemical performance of cathodes for lithium-ion (Li-ion) batteries. High energy planetary ball milling of LiNi1/3Mn1/3Co1/3O2 (NMC) cathode materials was investigated as a route to reduce the particle size and improve the electrochemical performance. The effect of ball milling times, milling speeds, and composition on the structure and properties of NMC cathodes was determined. X-ray diffraction analysis showed that ball milling decreased primary particle (crystallite) size by up to 29%, and the crystallite size was correlated with the milling time and milling speed. Using relatively mild milling conditions that provided an intermediate crystallite size, cathodes with higher capacities, improved rate capabilities, and improved capacity retention were obtained within 14 μm-thick electrode configurations. High milling speeds and long milling times not only resulted in smaller crystallite sizes but also lowered electrochemical performance. Beyond reduction in crystallite size, ball milling was found to increase the interfacial charge transfer resistance, lower the electrical conductivity, and produce aggregates that influenced performance. Computations support that electrolyte diffusivity within the cathode and film thickness play a significant role in the electrode performance. This study shows that cathodes with improved performance are obtained through use of mild ball milling conditions and appropriately designed electrodes that optimize the multiple transport phenomena involved in electrochemical charge storage materials.


Author(s):  
Jing Zhao ◽  
Hongye Yuan ◽  
Guiling Wang ◽  
Xiao Feng Lim ◽  
Hualin Ye ◽  
...  

The Cu-foil current collectors with Ni3(HITP)2 films were prepared to reduce the energy barrier of the current collector surface and thus provide a uniform seeding layer for the subsequent deposition of Li in Li-ion batteries.


2013 ◽  
Vol 239 ◽  
pp. 308-314 ◽  
Author(s):  
David Reyter ◽  
Steeve Rousselot ◽  
Driss Mazouzi ◽  
Magali Gauthier ◽  
Philippe Moreau ◽  
...  

2017 ◽  
Vol 41 (20) ◽  
pp. 11759-11765 ◽  
Author(s):  
Shu Huang ◽  
Jianguo Ren ◽  
Rong Liu ◽  
Min Yue ◽  
Youyuan Huang ◽  
...  

A crosslinked ionomer binder was prepared and used in graphite anodes for Li-ion batteries. These binder-based anodes exhibit enhanced electrochemical performance due to the formation of hydrogen bonds and the release of conductive Li+.


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