scholarly journals π+–π+ stacking of imidazolium cations enhances molecular layering of room temperature ionic liquids at their interfaces

2017 ◽  
Vol 19 (4) ◽  
pp. 2850-2856 ◽  
Author(s):  
Fujie Tang ◽  
Tatsuhiko Ohto ◽  
Taisuke Hasegawa ◽  
Mischa Bonn ◽  
Yuki Nagata
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Interfacial Structure ◽  
Molecular Polarizability ◽  
Room Temperature Ionic Liquids ◽  
Molecular Layering ◽  
Ordered Structure ◽  
Imidazolium Cations ◽  
Π Stacking

The interfacial structure of room temperature ionic liquids (RTILs) is governed by the competing effects of the randomization due to the molecular polarizability and the ordered structure stabilized by π+–π+ interactions between the cationic molecules of RTILs.

scholarly journals Structure and dynamics of room temperature ionic liquids with bromide anion: results from 81 Br NMR spectroscopy

2015 ◽  
Vol 53 (5) ◽  
pp. 369-378 ◽  
Author(s):  
Takatsugu Endo ◽  
Mamoru Imanari ◽  
Yuki Hidaka ◽  
Hiroko Seki ◽  
Keiko Nishikawa ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Nmr Spectroscopy ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Bromide Anion ◽  
Structure And Dynamics
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