Effect of HBr formation on mercury oxidation via CaBr2 addition to coal during combustion

RSC Advances ◽  
2016 ◽  
Vol 6 (64) ◽  
pp. 59009-59015 ◽  
Author(s):  
Yang Yang ◽  
Wenqing Xu ◽  
Yinghong Wu ◽  
Jin Xiong ◽  
Tingyu Zhu ◽  
...  

Adding CaBr2 to coal to enhance elemental mercury (Hg0) oxidation during combustion has been an effective mercury control technology, but the added CaBr2 may increase levels of noxious Br2 or HBr gases in flue gas.

2011 ◽  
Vol 45 (13) ◽  
pp. 5725-5730 ◽  
Author(s):  
Naiqiang Yan ◽  
Wanmiao Chen ◽  
Jie Chen ◽  
Zan Qu ◽  
Yongfu Guo ◽  
...  

2017 ◽  
Vol 40 (1) ◽  
pp. 29-36 ◽  
Author(s):  
Zhengcheng Wen ◽  
Zhihua Wang ◽  
Yuan Li ◽  
Kefa Cen

2018 ◽  
Vol 345 ◽  
pp. 578-585 ◽  
Author(s):  
Qiang Zhou ◽  
Yufeng Duan ◽  
Mingming Chen ◽  
Meng Liu ◽  
Ping Lu ◽  
...  

2011 ◽  
Vol 50 (10) ◽  
pp. 5914-5919 ◽  
Author(s):  
Meiyan Wang ◽  
Tianle Zhu ◽  
Hongjing Luo ◽  
Hong Wang ◽  
Weiyi Fan

2012 ◽  
Vol 610-613 ◽  
pp. 2033-2037 ◽  
Author(s):  
Yu Ze Jiang ◽  
Chuan Min Chen ◽  
Li Xing Jiang ◽  
Song Tao Liu ◽  
Bin Wang

Hg2+captured by wet flue gas desulfurization (WFGD) systems can easily be reduced by reducing substances such as S(IV) (SO32-or HSO3-) and results in emissions of elemental mercury (Hg0). The re-emission of Hg0would lead to a damping of the total mercury removal efficiency by WFGD systems. The effects of the operating conditions, which included the pH, temperature, Cl-concentrations and oxygen concentrations, on Hg0re-emission from WFGD liquors was carried out. The experimental results indicated that the Hg0re-emission rate from WFGD liquors increased as the operational temperatures and pH values increased. The Hg0re-emission rates decreased as the O2concentration of flue gas and Cl-concentration of WFGD liquors increased. So the Hg0re-emission from WFGD system can be reduced or slowed by decreasing the temperature and pH, or by using forced oxidation. The present findings could be valuable for industrial application of characterizing and optimizing mercury control in WFGD systems.


2018 ◽  
Vol 239 ◽  
pp. 233-244 ◽  
Author(s):  
Weichun Yang ◽  
Chaofang Li ◽  
Haiying Wang ◽  
Xingyao Li ◽  
Weilin Zhang ◽  
...  

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