Design and preparation of silica tube/poly(aryl ether ketone) composites with low dielectric constant

RSC Advances ◽  
2016 ◽  
Vol 6 (77) ◽  
pp. 72999-73005 ◽  
Author(s):  
Yaning Lu ◽  
Shuling Zhang ◽  
Zhi Geng ◽  
Yinlong Du ◽  
Kai Zhu ◽  
...  

Low dielectric constant porous composites in which uniform nanosized silica tubes are covalently bonding onto fluoropoly(aryl ether ketone) are prepared.

2013 ◽  
Vol 129 (6) ◽  
pp. 3219-3225 ◽  
Author(s):  
Zhi Geng ◽  
Shuling Zhang ◽  
Jianxin Mu ◽  
Xu Jiang ◽  
Pengfei Huo ◽  
...  

2012 ◽  
Vol 24 (8) ◽  
pp. 692-701 ◽  
Author(s):  
Chengyuan Shang ◽  
Xiaojuan Zhao ◽  
Junwei Li ◽  
Jingang Liu ◽  
Wei Huang

Two novel bisphenols, 1,1-bis(4′-hydroxy-3′,5′-dimethylphenyl)-1-(3′′-trifluoromethylphenyl)-2,2,2-trifluoroethane (4M6FDO) and 1,1-bis(4′-hydroxy-3′,5′-dimethylphenyl)-1-[3′′,5′′-bis(trifluoromethyl)phenyl]-2,2,2-trifluoroethane (4M9FDO), with methyl groups ortho-substituted to the phenol groups, bulky trifluoromethyl-substituted phenyl groups and trifluoromethyl groups in the structure, were synthesized and characterized. The bisphenols were polymerized with 4,4′-difluorobenzophenone and bis(4-fluorophenyl) sulfone, respectively, via a aromatic nucleophilic substitution polycondensation to afford four poly(aryl ether ketone/sulfone)s (PAEKs/PAESs) with the inherent viscosities of 0.32–0.52 dL g−1. The ortho-methyl and pendant trifluoromethyl-substituted phenyl groups endow the polymers with good solubility, the rigidity of the polymer chains increase the glass transition ( Tg) of the polymers to 197–235 °C. Flexible and tough films cast from N,N-dimethylacetamide showed good thermal stability, low dielectric constants of 2.67–2.73 and low water uptakes of 0.21–0.40%. Moreover, the polymers showed good transparency with light transmittance at 450 nm as high as 96% and cutoff wavelength as low as 285 nm. The PAEKs also exhibited low light-absorption at the optocommunication wavelengths of 1310 and 1550 nm.


2018 ◽  
Vol 135 (44) ◽  
pp. 46857 ◽  
Author(s):  
Yurong Zhang ◽  
Hao Jiang ◽  
Jie Liu ◽  
Chengji Zhao ◽  
Hui Na

2013 ◽  
Vol 63 (2) ◽  
pp. 333-337 ◽  
Author(s):  
Zhi Geng ◽  
Yaning Lu ◽  
Shuling Zhang ◽  
Xu Jiang ◽  
Pengfei Huo ◽  
...  

2005 ◽  
Vol 17 (8) ◽  
pp. 1056-1059 ◽  
Author(s):  
Y.-H. Zhang ◽  
S.-G. Lu ◽  
Y.-Q. Li ◽  
Z.-M. Dang ◽  
J. H. Xin ◽  
...  

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