High catalytic activity for CO oxidation on single Fe atom stabilized in graphene vacancies

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93985-93996 ◽  
Author(s):  
Yanan Tang ◽  
Jincheng Zhou ◽  
Zigang Shen ◽  
Weiguang Chen ◽  
Chenggang Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
First Principles ◽  
High Catalytic Activity ◽  
First Principles Method

The geometric, electronic and catalytic characters of Fe atom embedded graphene (including monovacancy and divacancy) are investigated using the first-principles method, which gives a reference on designing graphene-based catalysts for CO oxidation.

scholarly journals CO Oxidation Efficiency and Hysteresis Behavior over Mesoporous Pd/SiO2 Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 131 ◽  
Author(s):  
Rola Mohammad Al Soubaihi ◽  
Khaled Mohammad Saoud ◽  
Myo Tay Zar Myint ◽  
Mats A. Göthelid ◽  
Joydeep Dutta
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Active Sites ◽  
Bond Activation ◽  
Dissociative Adsorption ◽  
High Catalytic Activity ◽  
Good Catalytic Activity ◽  
Pretreatment Conditions ◽  
Oxidation Efficiency

Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO2 aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO bond activation capability and thermal stability. Pd/SiO2 catalysts were investigated using carbon monoxide (CO) oxidation as a model reaction. The catalyst becomes active, and the conversion increases after the temperature reaches the ignition temperature (Tig). A normal hysteresis in carbon monoxide (CO) oxidation has been observed, where the catalysts continue to exhibit high catalytic activity (CO conversion remains at 100%) during the extinction even at temperatures lower than Tig. The catalyst was characterized using BET, TEM, XPS, TGA-DSC, and FTIR. In this work, the influence of pretreatment conditions and stability of the active sites on the catalytic activity and hysteresis is presented. The CO oxidation on the Pd/SiO2 catalyst has been attributed to the dissociative adsorption of molecular oxygen and the activation of the C-O bond, followed by diffusion of adsorbates at Tig to form CO2. Whereas, the hysteresis has been explained by the enhanced stability of the active site caused by thermal effects, pretreatment conditions, Pd-SiO2 support interaction, and PdO formation and decomposition.

CO Oxidation on Inverse CeOx/Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O2

2011 ◽  
Vol 133 (10) ◽  
pp. 3444-3451 ◽  
Author(s):  
Fan Yang ◽  
Jesús Graciani ◽  
Jaime Evans ◽  
Ping Liu ◽  
Jan Hrbek ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
High Catalytic Activity

Synthesis and characterization of new isostructural series LnFe0.5Sb1.5O6 (Ln = La-Sm) exhibiting high catalytic activity in CO oxidation

2019 ◽  
Vol 777 ◽  
pp. 655-662 ◽  
Author(s):  
A.V. Egorysheva ◽  
O.G. Ellert ◽  
E. Yu Liberman ◽  
D.I. Kirdyankin ◽  
S.V. Golodukhina ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Synthesis And Characterization ◽  
High Catalytic Activity

A phosphorene-like InP3 monolayer: structure, stability, and catalytic properties toward the hydrogen evolution reaction

2020 ◽  
Vol 8 (3) ◽  
pp. 1307-1314 ◽  
Author(s):  
Abdul Jalil ◽  
Zhiwen Zhuo ◽  
Zhongti Sun ◽  
Fang Wu ◽  
Chuan Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
First Principles ◽  
Carrier Mobility ◽  
Catalytic Properties ◽  
Structure Stability ◽  
High Catalytic Activity ◽  
First Principles Calculations ◽  
Direct Bandgap

Phosphorene-like InP3 is reported with first-principles calculations, which is a direct-bandgap semiconductor with anisotropic carrier mobility and high catalytic activity toward the hydrogen evolution reaction.

scholarly journals Single Ni atom incorporated with pyridinic nitrogen graphene as an efficient catalyst for CO oxidation: first-principles investigation

RSC Advances ◽  
2017 ◽  
Vol 7 (77) ◽  
pp. 48819-48824 ◽  
Author(s):  
Mingguang Wang ◽  
Zhu Wang
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
First Principles ◽  
First Principles Calculations ◽  
Efficient Catalyst ◽  
Pyridinic Nitrogen

We have investigated the potential catalytic activity of a single Ni atom incorporated with pyridinic nitrogen graphene (Ni-3N-G) in CO oxidation with first-principles calculations.

Preparation of TiO2-supported twinned gold nanoparticles by CO treatment and their CO oxidation activity

2015 ◽  
Vol 51 (87) ◽  
pp. 15823-15826 ◽  
Author(s):  
Junya Ohyama ◽  
Taiki Koketsu ◽  
Yuta Yamamoto ◽  
Shigeo Arai ◽  
Atsushi Satsuma
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Au Nanoparticles ◽  
High Catalytic Activity ◽  
Oxidation Activity

Au/TiO2 prepared by CO treatment showed high catalytic activity for CO oxidation due to twinned structure of Au nanoparticles.

A highly moisture-resistant Fe-doped mesoporous Co3O4 catalyst for efficient low-temperature CO oxidation

2015 ◽  
Vol 39 (3) ◽  
pp. 1742-1748 ◽  
Author(s):  
Gengnan Li ◽  
Liang Li ◽  
Yongsheng Li ◽  
Jianlin Shi
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Co Oxidation ◽  
High Catalytic Activity ◽  
Low Temperature Co Oxidation ◽  
Moisture Conditions ◽  
Moisture Resistant

Compared with pure Co3O4 spinel, the Fe-doped catalyst demonstrates high catalytic activity and stability in low temperature CO oxidation under moisture conditions.

Origin of extraordinarily high catalytic activity of Co3O4 and its morphological chemistry for CO oxidation at low temperature

2012 ◽  
Vol 296 ◽  
pp. 110-119 ◽  
Author(s):  
Hai-Feng Wang ◽  
Richard Kavanagh ◽  
Yang-Long Guo ◽  
Yun Guo ◽  
Guanzhong Lu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Co Oxidation ◽  
High Catalytic Activity

Hollow and Core–Shell Nanostructure Co3O4 Derived from a Metal Formate Framework toward High Catalytic Activity of CO Oxidation

2018 ◽  
Vol 1 (2) ◽  
pp. 800-806 ◽  
Author(s):  
Chi Zhang ◽  
Li Zhang ◽  
Guancheng Xu ◽  
Xin Ma ◽  
Jinling Xu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Core Shell ◽  
High Catalytic Activity ◽  
Metal Formate
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