Preparation of TiO2-supported twinned gold nanoparticles by CO treatment and their CO oxidation activity

2015 ◽  
Vol 51 (87) ◽  
pp. 15823-15826 ◽  
Author(s):  
Junya Ohyama ◽  
Taiki Koketsu ◽  
Yuta Yamamoto ◽  
Shigeo Arai ◽  
Atsushi Satsuma
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Au Nanoparticles ◽  
High Catalytic Activity ◽  
Oxidation Activity

Au/TiO2 prepared by CO treatment showed high catalytic activity for CO oxidation due to twinned structure of Au nanoparticles.

Hollow silica nanostructures with small size Au nanoparticles for catalytic applications

RSC Advances ◽  
2016 ◽  
Vol 6 (92) ◽  
pp. 89057-89060 ◽  
Author(s):  
Lin Yao ◽  
Jong-Min Lee
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Au Nanoparticles ◽  
Tetraethyl Orthosilicate ◽  
High Catalytic Activity ◽  
Hollow Silica ◽  
Silica Nanostructures ◽  
Catalytic Applications

Hollow silica nanostructures synthesized using the silica precursors (3-aminopropyl) trimethoxysilane and tetraethyl orthosilicate provide support to small sized gold nanoparticles with a high catalytic activity for the reduction of 4-nitrophenol.

The Relation between Catalytic Activity of CO Oxidation and Support Structure in Oxidation Catalysts using Gold Nanoparticles

2005 ◽  
Vol 900 ◽  
Author(s):  
Shiho Nagano ◽  
Koji Tajiri ◽  
Yutaka Tai
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Preparation Method ◽  
Surface Condition ◽  
Silica Aerogels ◽  
High Catalytic Activity ◽  
Support Materials ◽  
Co Oxidation Reaction ◽  
The Difference

ABSTRACTThiol-passivated gold nanoparticles were adsorbed on several kinds of support materials such as titania-coated silica aerogels and xerogels etc., and then the thiol was removed by heat treatment. The catalytic activity of the prepared composites for CO oxidation reaction was measured, and the effects of the support on the catalytic activity were investigated. Density of the supports, namely, whether aerogel supports or xerogel ones, hardly affected the catalytic activity. It was found that the catalysts having high catalytic activity could be obtained by this preparation method, even using the xerogels as the support. Calcination of the supports before adsorption of the gold nanoparticles affected the activity. The difference of the catalytic activity was observed between the composites with same gold nanoparticle size, so it was considered that the surface condition of the support materials affects the state of gold nanoparticles in composite.

Preparation of Gold Nanoparticles Supported on Montmorillonite and its Catalytic Activity for CO Oxidation

2014 ◽  
Vol 955-959 ◽  
pp. 51-55
Author(s):  
Ting Ting Hu ◽  
Lin Hua Zhu
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Oxidation Reaction ◽  
Fluorescence Analysis ◽  
X Ray Diffraction ◽  
Oxidation Activity ◽  
X Ray ◽  
Transmission Electron ◽  
Gold Precursor

Gold catalysts supported on Na-MMT and Al-PILM noted as Au/Na-MMT and Au/Al-PILM respectively were prepared using Au(en)2Cl3 as precursor, and the catalytic oxidation activity for CO oxidation was investigated. The influence of different carriers on the conversion of CO was discussed. The phase of catalysts, the actual gold loading and the morphology of gold nanoparticles were characterized by X-ray diffraction(XRD), X-ray fluorescence analysis(XRF) and Transmission electron microscopy(TEM). The results showed that Au/Al-PILM exhibited higher catalytic activity for the oxidation reaction of CO, and 100% conversion of CO was achieved at reaction temperature of 250°C when gold precursor was loaded on the Al-PILM carrier at 60°Cand calcined it at 450°C for 1h.

In situ growth of small Au nanoparticles on ZnO nanorods via ultrasonic irradiation toward super-enhanced catalytic activity

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 107433-107441 ◽  
Author(s):  
Xueling Song ◽  
Xiao Zhang ◽  
Ping Yang
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Ultrasonic Irradiation ◽  
Photocatalytic Performance ◽  
Au Nanoparticles ◽  
Zno Nanorods ◽  
Sonochemical Method ◽  
In Situ Growth ◽  
Oxidation Activity

Au/ZnO NRs created via a sonochemical method exhibit superior photocatalytic performance and enhanced CO oxidation activity.

scholarly journals CO Oxidation Efficiency and Hysteresis Behavior over Mesoporous Pd/SiO2 Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 131 ◽  
Author(s):  
Rola Mohammad Al Soubaihi ◽  
Khaled Mohammad Saoud ◽  
Myo Tay Zar Myint ◽  
Mats A. Göthelid ◽  
Joydeep Dutta
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Active Sites ◽  
Bond Activation ◽  
Dissociative Adsorption ◽  
High Catalytic Activity ◽  
Good Catalytic Activity ◽  
Pretreatment Conditions ◽  
Oxidation Efficiency

Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO2 aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO bond activation capability and thermal stability. Pd/SiO2 catalysts were investigated using carbon monoxide (CO) oxidation as a model reaction. The catalyst becomes active, and the conversion increases after the temperature reaches the ignition temperature (Tig). A normal hysteresis in carbon monoxide (CO) oxidation has been observed, where the catalysts continue to exhibit high catalytic activity (CO conversion remains at 100%) during the extinction even at temperatures lower than Tig. The catalyst was characterized using BET, TEM, XPS, TGA-DSC, and FTIR. In this work, the influence of pretreatment conditions and stability of the active sites on the catalytic activity and hysteresis is presented. The CO oxidation on the Pd/SiO2 catalyst has been attributed to the dissociative adsorption of molecular oxygen and the activation of the C-O bond, followed by diffusion of adsorbates at Tig to form CO2. Whereas, the hysteresis has been explained by the enhanced stability of the active site caused by thermal effects, pretreatment conditions, Pd-SiO2 support interaction, and PdO formation and decomposition.

CO Oxidation on Inverse CeOx/Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O2

2011 ◽  
Vol 133 (10) ◽  
pp. 3444-3451 ◽  
Author(s):  
Fan Yang ◽  
Jesús Graciani ◽  
Jaime Evans ◽  
Ping Liu ◽  
Jan Hrbek ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
High Catalytic Activity

Synthesis and characterization of new isostructural series LnFe0.5Sb1.5O6 (Ln = La-Sm) exhibiting high catalytic activity in CO oxidation

2019 ◽  
Vol 777 ◽  
pp. 655-662 ◽  
Author(s):  
A.V. Egorysheva ◽  
O.G. Ellert ◽  
E. Yu Liberman ◽  
D.I. Kirdyankin ◽  
S.V. Golodukhina ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Synthesis And Characterization ◽  
High Catalytic Activity

High catalytic activity for CO oxidation on single Fe atom stabilized in graphene vacancies

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93985-93996 ◽  
Author(s):  
Yanan Tang ◽  
Jincheng Zhou ◽  
Zigang Shen ◽  
Weiguang Chen ◽  
Chenggang Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
First Principles ◽  
High Catalytic Activity ◽  
First Principles Method

The geometric, electronic and catalytic characters of Fe atom embedded graphene (including monovacancy and divacancy) are investigated using the first-principles method, which gives a reference on designing graphene-based catalysts for CO oxidation.

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