A cathode material for lithium-ion batteries based on graphitized carbon-wrapped FeF3 nanoparticles prepared by facile polymerization

2016 ◽  
Vol 4 (38) ◽  
pp. 14857-14864 ◽  
Author(s):  
T. Kim ◽  
W. J. Jae ◽  
H. Kim ◽  
M. Park ◽  
J.-M. Han ◽  
...  

FeF3/graphitic carbon composites are successfully synthesized, showing high electrochemical performances as a cathode material for Li-ion batteries.

CrystEngComm ◽  
2015 ◽  
Vol 17 (32) ◽  
pp. 6163-6174 ◽  
Author(s):  
L. de Biasi ◽  
G. Lieser ◽  
J. Rana ◽  
S. Indris ◽  
C. Dräger ◽  
...  

For possible future application as cathode material in lithium ion batteries, the lithium insertion mechanism of trirutile-type LiNiFeF6 was investigated.


Energies ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 827 ◽  
Author(s):  
Ying Liu ◽  
Xueying Li ◽  
Anupriya K. Haridas ◽  
Yuanzheng Sun ◽  
Jungwon Heo ◽  
...  

Lithium ion (Li-ion) batteries have been widely applied to portable electronic devices and hybrid vehicles. In order to further enhance performance, the search for advanced anode materials to meet the growing demand for high-performance Li-ion batteries is significant. Fe3C as an anode material can contribute more capacity than its theoretical one due to the pseudocapacity on the interface. However, the traditional synthetic methods need harsh conditions, such as high temperature and hazardous and expensive chemical precursors. In this study, a graphitic carbon encapsulated Fe/Fe3C (denoted as Fe/Fe3C@GC) composite was synthesized as an anode active material for high-performance lithium ion batteries by a simple and cost-effective approach through co-pyrolysis of biomass and iron precursor. The graphitic carbon shell formed by the carbonization of sawdust can improve the electrical conductivity and accommodate volume expansion during discharging. The porous microstructure of the shell can also provide increased active sites for the redox reactions. The in-situ-formed Fe/Fe3C nanoparticles show pseudocapacitive behavior that increases the capacity. The composite exhibits a high reversible capacity and excellent rate performance. The composite delivered a high initial discharge capacity of 1027 mAh g−1 at 45 mA g−1 and maintained a reversible capacity of 302 mAh g−1 at 200 mA g−1 after 200 cycles. Even at the high current density of 5000 mA g−1, the Fe/Fe3C@GC cell also shows a stable cycling performance. Therefore, Fe/Fe3C@GC composite is considered as one of the potential anode materials for lithium ion batteries.


2019 ◽  
Vol 9 (2) ◽  
pp. 3866-3873

Composites of {[(1-x-y) LiFe0.333Ni0.333 Co0.333] PO4}, xLi2FePO4F and yLiCoPO4system were synthesized using the sol-gel method. Stoichiometric weights of the mole-fraction of LiOH, FeCl2·4H2O and H3PO4, LiCl, Ni(NO3)2⋅6H2O, Co(Ac)2⋅4H2O, as starting materials of lithium, Iron, Nickel , and Cobalt, in 7 samples of the system, respectively. We exhibited Li1.167 Ni0.222 Co0.389 Fe0.388 PO4 is the best composition for cathode material in this study. Obviously, the used weight of cobalt in these samples is lower compared with LiCoO2 that is an advantage in view point of cost in this study. Charge-discharge haracteristics of the mentioned cathode materials were investigated by performing cycle tests in the range of 2.4–3.8 V (versus Li/Li+). Our results confirmed, although these kind systems can help for removing the disadvantage of cobalt which mainly is its cost and toxic, the performance of these kind systems are similar to the commercial cathode materials in Lithium Ion batteries (LIBs).


Nanoscale ◽  
2019 ◽  
Vol 11 (18) ◽  
pp. 8803-8811 ◽  
Author(s):  
Renpeng Chen ◽  
Xiaolan Xue ◽  
Jingyu Lu ◽  
Tao Chen ◽  
Yi Hu ◽  
...  

Flexible and free-standing NiSb@NCNF electrodes are prepared and they exhibit remarkable electrochemical performances for lithium ion batteries.


RSC Advances ◽  
2015 ◽  
Vol 5 (62) ◽  
pp. 50316-50323 ◽  
Author(s):  
Hai Zhu ◽  
Xiaoling Ma ◽  
Ling Zan ◽  
Youxiang Zhang

Effects of V2O5 nanowires on the performances of Li2MnSiO4 as cathode materials for Li-ion batteries were tested and analyzed.


RSC Advances ◽  
2015 ◽  
Vol 5 (7) ◽  
pp. 4872-4879 ◽  
Author(s):  
Mansoo Choi ◽  
Kisuk Kang ◽  
Hyun-Soo Kim ◽  
Young Moo Lee ◽  
Bong-Soo Jin

We report high capacity and rate capability of titanium-added Li3V2(PO4)3 (LVP) as a cathode material for lithium ion batteries (LIBs).


2019 ◽  
Vol 7 (26) ◽  
pp. 15766-15773 ◽  
Author(s):  
Gi Dae Park ◽  
Jeong Hoo Hong ◽  
Dae Soo Jung ◽  
Jong-Heun Lee ◽  
Yun Chan Kang

Unique structured microspheres with multishells comprising graphitic carbon-coated Fe3O4 hollow nanopowders are successfully synthesized as an efficient anode material for lithium-ion batteries


Nanoscale ◽  
2019 ◽  
Vol 11 (28) ◽  
pp. 13282-13288 ◽  
Author(s):  
Renpeng Chen ◽  
Xiaolan Xue ◽  
Yi Hu ◽  
Weihua Kong ◽  
Huinan Lin ◽  
...  

Free-standing and flexible SnSb-CNTs@NCNFs electrodes are prepared and exhibit excellent electrochemical performances for lithium ion batteries.


2015 ◽  
Vol 44 (1) ◽  
pp. 138-145 ◽  
Author(s):  
He Gao ◽  
Sen Zhang ◽  
Chao Deng

Li9Fe3(P2O7)3(PO4)2 with mixed-polyanion groups is introduced as a novel cathode material for Li-ion batteries.


2014 ◽  
Vol 2 (19) ◽  
pp. 6870-6878 ◽  
Author(s):  
Jinlong Yang ◽  
Xiaochun Kang ◽  
Lin Hu ◽  
Xue Gong ◽  
Shichun Mu

The nanocrystalline-Li2FeSiO4 with carbon frameworks, possessing high-capacity and high-rate performance, is a promising next-generation cathode material for high-power lithium-ion batteries.


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