Galvanic replacement reaction: recent developments for engineering metal nanostructures towards catalytic applications

Recent developments to achieve further physicochemical control in metallic nanomaterials by galvanic replacement are discussed towards applications in catalysis.

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Effects of Ar or O2Gas Bubbling for Shape, Size, and Composition Changes in Silver-Gold Alloy Nanoparticles Prepared from Galvanic Replacement Reaction

Journal of Nanomaterials ◽

10.1155/2013/425071 ◽

2013 ◽

Vol 2013 ◽

pp. 1-10

Author(s):

Md. Jahangir Alam ◽

Masaharu Tsuji

Keyword(s):

Ag Nanoparticles ◽

Major Product ◽

Metal Nanostructures ◽

Galvanic Replacement ◽

Silver Nanostructures ◽

Alloy Nanoparticles ◽

Galvanic Replacement Reaction ◽

Replacement Reaction ◽

Gas Bubbling ◽

Composition Changes

The galvanic replacement reaction between silver nanostructures andAuCl4-solution has recently been demonstrated as a versatile method for generating metal nanostructures with hollow interiors. Here we describe the results of a systematic study detailing the morphological, structural, compositional, and spectral changes involved in such a heterogeneous reaction on the nanoscale. Effects of Ar or O2gas bubbling for the formation of Ag-Au alloy nanoparticles by the galvanic replacement between spherical Ag nanoparticles andAuCl4-especially were studied in ethylene glycol (EG) at150°C. The shape, size, and composition changes occur rapidly under O2bubbling in comparison with those under Ar bubbling. The major product after 60 min heating under Ar gas bubbling was perforated Ag-Au alloy particles formed by the replacement reaction and the minor product was ribbon-type particles produced from splitting off some perforated particles. On the other hand, the major product after 60 min heating under O2gas bubbling was ribbon-type particles. In addition, small spherical Ag particles are produced. They are formed through rereduction of Ag+ions released from the replacement reaction and oxidative etching of Ag nanoparticles by O2/Cl−in EG.

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Galvanic replacement reaction: A simple and powerful route to hollow and porous metal nanostructures

Proceedings of the Institution of Mechanical Engineers Part N Journal of Nanoengineering and Nanosystems ◽

10.1243/17403499jnn111 ◽

2007 ◽

Vol 221 (1) ◽

pp. 1-16 ◽

Cited By ~ 22

Author(s):

Xianmao Lu ◽

Jingyi Chen ◽

S E Skrabalak ◽

Younan Xia

Keyword(s):

Porous Metal ◽

Metal Nanostructures ◽

Galvanic Replacement ◽

Galvanic Replacement Reaction ◽

Replacement Reaction

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Controllable Loading of Noble Metal Nanoparticles on Multiwalled Carbon Nanotubes/Fe3O4through an In Situ Galvanic Replacement Reaction for High-Performance Catalysis

ChemCatChem ◽

10.1002/cctc.201402167 ◽

2014 ◽

Vol 6 (7) ◽

pp. 1868-1872 ◽

Cited By ~ 16

Author(s):

Shu-Liang Yang ◽

Chang-Yan Cao ◽

Fang-Fang Wei ◽

Pei-Pei Huang ◽

Yong-Bin Sun ◽

...

Keyword(s):

Carbon Nanotubes ◽

Metal Nanoparticles ◽

Multiwalled Carbon Nanotubes ◽

High Performance ◽

Noble Metal Nanoparticles ◽

Galvanic Replacement ◽

Galvanic Replacement Reaction ◽

Replacement Reaction ◽

Multiwalled Carbon

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Magneto-Revealing and Acceleration of Hidden Kirkendall Effect in Galvanic Replacement Reaction

The Journal of Physical Chemistry Letters ◽

10.1021/acs.jpclett.1c01327 ◽

2021 ◽

pp. 5294-5300

Author(s):

Yuecheng Bian ◽

Wei Ding ◽

Lin Hu ◽

Xiaoguang Zhu ◽

Yuping Sun ◽

...

Keyword(s):

Kirkendall Effect ◽

Galvanic Replacement ◽

Galvanic Replacement Reaction ◽

Replacement Reaction

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Mechanistic study on galvanic replacement reaction and synthesis of Ag-Au alloy nanoboxes with good surface- enhanced Raman scattering activity to detect melamine

Sensors and Actuators B Chemical ◽

10.1016/j.snb.2018.02.112 ◽

2018 ◽

Vol 263 ◽

pp. 274-280 ◽

Cited By ~ 4

Author(s):

Guanhua Lin ◽

Wenjie Dong ◽

Cong Wang ◽

Wensheng Lu

Keyword(s):

Raman Scattering ◽

Surface Enhanced Raman Scattering ◽

Mechanistic Study ◽

Galvanic Replacement ◽

Galvanic Replacement Reaction ◽

Replacement Reaction ◽

Good Surface ◽

Surface Enhanced ◽

Surface Enhanced Raman ◽

Enhanced Raman Scattering

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Bimetallic Cu–Pd alloy multipods and their highly electrocatalytic performance for formic acid oxidation and oxygen reduction

Journal of Materials Chemistry A ◽

10.1039/c6ta10476b ◽

2017 ◽

Vol 5 (9) ◽

pp. 4421-4429 ◽

Cited By ~ 117

Author(s):

Dong Chen ◽

Pengcheng Sun ◽

Hui Liu ◽

Jun Yang

Keyword(s):

Formic Acid ◽

Oxygen Reduction ◽

Formic Acid Oxidation ◽

Acid Oxidation ◽

Galvanic Replacement ◽

Galvanic Replacement Reaction ◽

Replacement Reaction ◽

Electrocatalytic Performance ◽

Pd Alloy

Nanoscale Cu–Pd alloy multipods were synthesized via the galvanic replacement reaction for catalyzing formic acid oxidation and oxygen reduction.

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Bismuth-induced synthesis of Au–X (X = Pt, Pd) nanoalloys for electrocatalytic reactions

Chemical Communications ◽

10.1039/d0cc06745h ◽

2021 ◽

Author(s):

Nan Wang ◽

Wei Zhao ◽

Miaolei Zhang ◽

Pengfei Cao ◽

Shengjun Sun ◽

...

Keyword(s):

Galvanic Replacement ◽

Galvanic Replacement Reaction ◽

Replacement Reaction ◽

Reaction Method ◽

Electrocatalytic Reaction ◽

Electrocatalytic Reactions

The synthesis of Au–X (X = Pt, Pd) nanoalloys based on Bi as an intermediate using the galvanic replacement reaction method for electrocatalytic reaction.

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