scholarly journals The contradictory effect of the methoxy-substituent in palladium-catalyzed ethylene/methyl acrylate cooligomerization

2018 ◽  
Vol 47 (8) ◽  
pp. 2778-2790 ◽  
Author(s):  
V. Rosar ◽  
A. Meduri ◽  
T. Montini ◽  
P. Fornasiero ◽  
E. Zangrando ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Methoxy Group ◽  
Palladium Complexes ◽  
Ancillary Ligand ◽  
Aryl Ring ◽  
Remarkable Effect ◽  
Palladium Catalyzed ◽  
Methoxy Substituent ◽  
Ethylene Methyl Acrylate ◽  
Catalytic Performances

Three new α-diimines bearing at least one methoxy group on one aryl ring were investigated. The introduction of the methoxy substituent on the ancillary ligand had a remarkable effect on the catalytic performances of the relevant palladium complexes.

Palladium-Catalyzed Ethylene/Methyl Acrylate Cooligomerization: Effect of a New Nonsymmetric α-Diimine

ChemCatChem ◽  
2012 ◽  
Vol 5 (5) ◽  
pp. 1170-1183 ◽  
Author(s):  
Angelo Meduri ◽  
Tiziano Montini ◽  
Fabio Ragaini ◽  
Paolo Fornasiero ◽  
Ennio Zangrando ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Palladium Catalyzed ◽  
Ethylene Methyl Acrylate

Palladium-Catalyzed Ethylene/Methyl Acrylate Co-Oligomerization: The Effect of a New Nonsymmetrical α-Diimine with the 1,4-Diazabutadiene Skeleton

ChemCatChem ◽  
2017 ◽  
Vol 9 (17) ◽  
pp. 3402-3411 ◽  
Author(s):  
Vera Rosar ◽  
Tiziano Montini ◽  
Gabriele Balducci ◽  
Ennio Zangrando ◽  
Paolo Fornasiero ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Palladium Catalyzed ◽  
Ethylene Methyl Acrylate

Analogies and Differences in Palladium-Catalyzed CO/Styrene and Ethylene/Methyl Acrylate Copolymerization Reactions

ChemCatChem ◽  
2014 ◽  
Vol 6 (8) ◽  
pp. 2403-2418 ◽  
Author(s):  
Vera Rosar ◽  
Angelo Meduri ◽  
Tiziano Montini ◽  
Francesco Fini ◽  
Carla Carfagna ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Palladium Catalyzed ◽  
Ethylene Methyl Acrylate

scholarly journals Palladium-Catalyzed Ethylene/Methyl Acrylate Copolymerization: Moving from the Acenaphthene to the Phenanthrene Skeleton of α-Diimine Ligands

2019 ◽  
Vol 38 (19) ◽  
pp. 3498-3511 ◽  
Author(s):  
Anna Dall’Anese ◽  
Vera Rosar ◽  
Luca Cusin ◽  
Tiziano Montini ◽  
Gabriele Balducci ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Diimine Ligands ◽  
Palladium Catalyzed ◽  
Ethylene Methyl Acrylate

Mono- and Bidentate Phosphine Ligands in the Palladium-Catalyzed Methyl Acrylate Dimerization

2003 ◽  
Vol 345 (3) ◽  
pp. 402-409 ◽  
Author(s):  
Jörg Zimmermann ◽  
Igor Tkatchenko ◽  
Peter Wasserscheid
Keyword(s):  
Methyl Acrylate ◽  
Phosphine Ligands ◽  
Palladium Catalyzed ◽  
Bidentate Phosphine

scholarly journals Influence of colemanite on the fire retardancy of ethylene-vinyl acetate and ethylene-methyl acrylate copolymers

2017 ◽  
Vol 144 ◽  
pp. 401-410 ◽  
Author(s):  
Florian Cavodeau ◽  
Amandine Viretto ◽  
Belkacem Otazaghine ◽  
José-Marie Lopez-Cuesta ◽  
Christelle Delaite
Keyword(s):  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Ethylene Vinyl Acetate ◽  
Fire Retardancy ◽  
Ethylene Methyl Acrylate

scholarly journals Combined directed ortho-zincation and palladium-catalyzed strategies: Synthesis of 4,n-dimethoxy-substituted benzo[b]furans

2011 ◽  
Vol 7 ◽  
pp. 1255-1260 ◽  
Author(s):  
Verónica Guilarte ◽  
M Pilar Castroviejo ◽  
Estela Álvarez ◽  
Roberto Sanz
Keyword(s):  
Methoxy Group ◽  
Sonogashira Coupling ◽  
Furan Derivatives ◽  
Iodination Reaction ◽  
Palladium Catalyzed

A new route to regioselectively dialkoxy-functionalized benzo[b]furan derivatives has been developed from 3-halo-2-iodoanisoles bearing an additional methoxy group, which have been accessed through an ortho-zincation/iodination reaction. Two palladium-catalyzed processes, namely a Sonogashira coupling followed by a tandem hydroxylation/cyclization sequence, give rise to new and interesting dimethoxy-substituted benzo[b]furans.

scholarly journals Crystal structures of three 3,4,5-trimethoxybenzamide-based derivatives

2016 ◽  
Vol 72 (5) ◽  
pp. 675-682 ◽  
Author(s):  
Ligia R. Gomes ◽  
John Nicolson Low ◽  
Catarina Oliveira ◽  
Fernando Cagide ◽  
Fernanda Borges
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Crystal Structures ◽  
Methoxy Group ◽  
Combined Effect ◽  
Donor Group ◽  
Methoxy Substituent ◽  
A Chain ◽  
Benzamide Derivatives

The crystal structures of three benzamide derivatives,viz. N-(6-hydroxyhexyl)-3,4,5-trimethoxybenzamide, C16H25NO5, (1),N-(6-anilinohexyl)-3,4,5-trimethoxybenzamide, C22H30N2O4, (2), andN-(6,6-diethoxyhexyl)-3,4,5-trimethoxybenzamide, C20H33NO6, (3), are described. These compounds differ only in the substituent at the end of the hexyl chain and the nature of these substituents determines the differences in hydrogen bonding between the molecules. In each molecule, them-methoxy substituents are virtually coplanar with the benzyl ring, while thep-methoxy substituent is almost perpendicular. The carbonyl O atom of the amide rotamer istransrelated with the amidic H atom. In each structure, the benzamide N—H donor group and O acceptor atoms link the molecules intoC(4) chains. In1, a terminal –OH group links the molecules into aC(3) chain and the combined effect of theC(4) andC(3) chains is a ribbon made up of screw relatedR22(17) rings in which the ...O—H... chain lies in the centre of the ribbon and the trimethoxybenzyl groups forms the edges. In2, the combination of the benzamideC(4) chain and the hydrogen bond formed by the terminal N—H group to an O atom of the 4-methoxy group link the molecules into a chain ofR22(17) rings. In3, the molecules are linked only byC(4) chains.

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