Photoinduced Fe-mediated atom transfer radical polymerization in aqueous media

2017 ◽  
Vol 8 (47) ◽  
pp. 7360-7368 ◽  
Author(s):  
Chao Bian ◽  
Yin-Ning Zhou ◽  
Jun-Kang Guo ◽  
Zheng-Hong Luo
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Aqueous Media ◽  
Atom Transfer ◽  
Fe Catalyst ◽  
First Time

Photoinduced atom transfer radical polymerization with an Fe catalyst was successfully performed in aqueous media for the first time.

Intramolecular photoinitiator induced atom transfer radical polymerization for electrochemical DNA detection

The Analyst ◽  
2020 ◽  
Vol 145 (3) ◽  
pp. 858-864
Author(s):  
Ligang Ma ◽  
Qianrui Liu ◽  
Lihe Jian ◽  
Shan Ye ◽  
Xiaoke Zheng ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Electrochemical Biosensor ◽  
Dna Detection ◽  
Atom Transfer ◽  
Highly Sensitive ◽  
Electrochemical Dna Detection ◽  
First Time

A novel electrochemical biosensor was reported for the first time to achieve highly sensitive DNA detection based on photoinduced atom transfer radical polymerization (photoATRP).

Application of novel ionic liquids for reverse atom transfer radical polymerization of methacrylonitrile without any additional ligand

2009 ◽  
Vol 24 (5) ◽  
pp. 1880-1885 ◽  
Author(s):  
Hou Chen ◽  
Yanfeng Meng ◽  
Ying Liang ◽  
Zixuan Lu ◽  
Pingli Lv
Keyword(s):  
Molecular Weight ◽  
Ionic Liquids ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Reaction Rate ◽  
Atom Transfer ◽  
Additional Ligand ◽  
Rapid Reaction ◽  
Living Nature ◽  
First Time

Reverse atom transfer radical polymerization of methacrylonitrile (MAN) initiated by azobisisobutyronitrile (AIBN) was approached for the first time in the absence of any ligand in four novel ionic liquids, 1-methylimidazolium acetate ([mim][AT]), 1-methylimidazolium butyrate ([mim][BT]), 1-methylimidazolium caproate ([mim][CT]), and 1-methylimidazolium heptylate ([mim][HT]). The polymerization in [mim][AT] not only showed the best control of molecular weight and its distribution but also provided a more rapid reaction rate with the ratio of [MAN]:[FeCl3]:[AIBN] at 300:2:1. The block copolymer PMAN-b-PSt was obtained via a conventional ATRP process in [mim][AT] by using the resulting PMAN as a macroinitiator. After simple purification, [mim][AT] and FeCl3 could be easily recycled and reused and had no effect on the living nature of reverse atom transfer radical polymerization of MAN.

Photoinduced Atom Transfer Radical Polymerization with ppm-Level Cu Catalyst by Visible Light in Aqueous Media

2015 ◽  
Vol 137 (49) ◽  
pp. 15430-15433 ◽  
Author(s):  
Xiangcheng Pan ◽  
Nikhil Malhotra ◽  
Antonina Simakova ◽  
Zongyu Wang ◽  
Dominik Konkolewicz ◽  
...  
Keyword(s):  
Visible Light ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Aqueous Media ◽  
Atom Transfer ◽  
Cu Catalyst ◽  
Ppm Level

scholarly journals Effect of Surface Charge on Surface-Initiated Atom Transfer Radical Polymerization from Cellulose Nanocrystals in Aqueous Media

2016 ◽  
Vol 17 (4) ◽  
pp. 1404-1413 ◽  
Author(s):  
Justin O. Zoppe ◽  
Xingyu Xu ◽  
Cindy Känel ◽  
Paola Orsolini ◽  
Gilberto Siqueira ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Surface Charge ◽  
Radical Polymerization ◽  
Cellulose Nanocrystals ◽  
Aqueous Media ◽  
Atom Transfer ◽  
Effect Of Surface

Synthesis and characterization of polystyrene-graft-polythiophene via a combination of atom transfer radical polymerization and Grignard reaction

RSC Advances ◽  
2014 ◽  
Vol 4 (32) ◽  
pp. 16792-16802 ◽  
Author(s):  
Maryam Hatamzadeh ◽  
Mehdi Jaymand
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Synthesis And Characterization ◽  
Grignard Reaction ◽  
Atom Transfer ◽  
First Time

For the first time, synthesis and characterization of polystyrene-graft-polythiopheneviaa combination of atom transfer radical polymerization and Grignard reaction is reported.

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