Graphene enhanced silicon/carbon composite as anode for high performance lithium-ion batteries

Silicon-based anode materials for lithium ion batteries (LIBs) have become a hot research topic due to their remarkably high theoretical capacity (4200 mA h g−1).

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Review-Recent development on silicon-based anodes for high-performance Lithium-Ion Batteries

E3S Web of Conferences ◽

10.1051/e3sconf/202125203004 ◽

2021 ◽

Vol 252 ◽

pp. 03004

Author(s):

Chengwei Zhang

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

High Performance ◽

Specific Capacity ◽

Lithium Ion ◽

Carbon Composite ◽

Existing Problems ◽

Silicon Carbon ◽

Theoretical Specific Capacity ◽

Silicon Based

Silicon has been recognized as one of the most promising anode materials for lithium-ion batteries (LIBs) due to its high theoretical specific capacity and similar working voltage as the lithium anode. However, there are some unavoidable drawbacks including volume expansion effects, low conductivity, the constant formation of SEI during lithiation and delithiation contributes to its fewer possibilities for commercialization. Therefore, modification of silicon for better performance is required for future applications. This review demonstrates recent progress and development of modification for the silicon-based anode including silicon-carbon composite with yolk-shell structure, nanostructured silicon, and alloying method. Finally, the existing problems and future improvements are also discussed based on current development.

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High performance silicon carbon composite anode materials for lithium ion batteries

Journal of Power Sources ◽

10.1016/j.jpowsour.2008.12.068 ◽

2009 ◽

Vol 189 (1) ◽

pp. 16-21 ◽

Cited By ~ 43

Author(s):

Zhaojun Luo ◽

Dongdong Fan ◽

Xianlong Liu ◽

Huanyu Mao ◽

Caifang Yao ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

High Performance ◽

Lithium Ion ◽

Carbon Composite ◽

Composite Anode ◽

Silicon Carbon

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Micro-Sized Silicon-Carbon Composite Composed of Carbon-Coated Sub-10 Nm Si Primary Particles As High-Performance Anode Materials for Lithium-Ion Batteries

ECS Meeting Abstracts ◽

10.1149/ma2014-01/1/3 ◽

2014 ◽

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

High Performance ◽

Lithium Ion ◽

Carbon Composite ◽

Silicon Carbon ◽

Primary Particles ◽

Carbon Coated

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Mesoporous silicon/carbon hybrids with ordered pore channel retention and tunable carbon incorporated content as high performance anode materials for lithium-ion batteries

Energy ◽

10.1016/j.energy.2015.03.090 ◽

2015 ◽

Vol 85 ◽

pp. 159-166 ◽

Cited By ~ 25

Author(s):

Qun Li ◽

Longwei Yin ◽

Jingyun Ma ◽

Zhaoqiang Li ◽

Zhiwei Zhang ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

High Performance ◽

Lithium Ion ◽

Pore Channel ◽

Mesoporous Silicon ◽

Silicon Carbon

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The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries

RSC Advances ◽

10.1039/c7ra12027c ◽

2018 ◽

Vol 8 (12) ◽

pp. 6660-6666 ◽

Cited By ~ 11

Author(s):

Jun Wang ◽

Shengli Li ◽

Yi Zhao ◽

Juan Shi ◽

Lili Lv ◽

...

Keyword(s):

Electrochemical Performance ◽

Lithium Ion Batteries ◽

Anode Materials ◽

Specific Capacity ◽

Lithium Ion ◽

Lithium Ions ◽

High Specific Capacity ◽

Silicon Carbon ◽

Silicon Based

With a high specific capacity (4200 mA h g−1), silicon based materials have become the most promising anode materials in lithium-ions batteries.

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Converting micro-sized kerf-loss silicon waste to high-performance hollow-structured silicon/carbon composite anodes for lithium-ion batteries

Sustainable Energy & Fuels ◽

10.1039/d0se00831a ◽

2020 ◽

Vol 4 (9) ◽

pp. 4780-4788 ◽

Cited By ~ 1

Author(s):

Qiang Ma ◽

Jiakang Qu ◽

Xiang Chen ◽

Zhuqing Zhao ◽

Yan Zhao ◽

...

Keyword(s):

Lithium Ion Batteries ◽

High Performance ◽

Low Cost ◽

Lithium Ion ◽

Carbon Composite ◽

Lithium Storage ◽

Practical Applications ◽

Storage Performance ◽

Silicon Carbon ◽

Composite Anodes

Low-cost feedstocks and rationally designed structures are the keys to determining the lithium-storage performance and practical applications of Si-based anodes for lithium-ion batteries (LIBs).

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Designing of hierarchical mesoporous/macroporous silicon-based composite anode material for low-cost high-performance lithium-ion batteries

Journal of Materials Chemistry A ◽

10.1039/c8ta11684a ◽

2019 ◽

Vol 7 (8) ◽

pp. 3874-3881 ◽

Cited By ~ 18

Author(s):

Min Cui ◽

Lin Wang ◽

Xianwei Guo ◽

Errui Wang ◽

Yubo Yang ◽

...

Keyword(s):

Composite Material ◽

Lithium Ion Batteries ◽

Anode Materials ◽

High Performance ◽

Low Cost ◽

Lithium Ion ◽

Macroporous Silicon ◽

Composite Anode ◽

Protective Layers ◽

Silicon Based

A mass-produced and low-cost hierarchical mesoporous/macroporous silicon-based composite material with an ample porous structure and dual carbon protective layers has been rationally designed and constructed. The Si/SiO2@C composite anode materials for LIBs show enhanced electrochemical properties.

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A 3D pore-nest structured silicon–carbon composite as an anode material for high performance lithium-ion batteries

Inorganic Chemistry Frontiers ◽

10.1039/c7qi00463j ◽

2017 ◽

Vol 4 (12) ◽

pp. 1996-2004 ◽

Cited By ~ 13

Author(s):

Yankai Li ◽

Zhi Long ◽

Pengyuan Xu ◽

Yang Sun ◽

Kai Song ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Material ◽

Current Density ◽

High Performance ◽

Lithium Ion ◽

Carbon Composite ◽

Nest Structure ◽

Composite Anode ◽

Silicon Carbon ◽

A Current

A novel silicon–carbon composite with a 3D pore-nest structure denoted as Si@SiOx/CNTs@C was prepared and studied, and the capacity of a Si@SiOx/CNTs@C composite anode can be maintained at above 1740 mA h g−1 at a current density of 0.42 A g−1 after 700 cycles.

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