Type and concentration of nanoparticles inside polymers can help or limit the chain portability and lead to diminishing or expanding electric encasing on connect or cutoff for versatile accuse and the development of charge transporters, especially polymer dielectrics. This chapter sheds light on the degradation of nanodielectrics which handled the electrical degradation and lifetime. The chapter contains also the different nanodielectrics thin films and presents the effect of degradation of nanodielectrics under AC and DC electric fields. It contains details about thermal stability analysis. Finally, this chapter draws attention on the recommendation for investment nanodielectrics technologies.