Easily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones

2018 ◽  
Vol 54 (50) ◽  
pp. 6843-6846 ◽  
Author(s):  
Milan Kumar Bisai ◽  
Tamal Das ◽  
Kumar Vanka ◽  
Sakya S. Sen

Simple and readily accessible lithium compounds are found to be efficient single site catalysts for cyanosilylation and hydroboration of a range of aldehydes and ketones under ambient conditions.

2019 ◽  
Vol 55 (78) ◽  
pp. 11711-11714 ◽  
Author(s):  
Milan Kumar Bisai ◽  
Sandeep Yadav ◽  
Tamal Das ◽  
Kumar Vanka ◽  
Sakya S. Sen

Readily accessible lithium compounds have been employed to catalyze the hydroboration of alkene and alkynes including terpenes using HBpin with anti-Markovnikov selectivity. The mechanism is proposed on the basis of experimental and DFT studies.


ChemCatChem ◽  
2017 ◽  
Vol 10 (1) ◽  
pp. 42-61 ◽  
Author(s):  
Jianming Huang ◽  
Zhaohe Liu ◽  
Dongmei Cui ◽  
Xinli Liu

ACS Nano ◽  
2018 ◽  
Vol 12 (6) ◽  
pp. 5903-5912 ◽  
Author(s):  
Dwaipayan Ghosh ◽  
Benny Febriansyah ◽  
Disha Gupta ◽  
Leonard Kia-Sheun Ng ◽  
Shibo Xi ◽  
...  

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