High proton conduction behavior in 12-connected 3D porous lanthanide–organic frameworks and their polymer composites

CrystEngComm ◽  
2018 ◽  
Vol 20 (22) ◽  
pp. 3066-3073 ◽  
Author(s):  
Shuai-Liang Yang ◽  
Pei-Pei Sun ◽  
Yue-Ying Yuan ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang
Keyword(s):  
Metal Ions ◽  
Polymer Composites ◽  
Composite Membranes ◽  
Proton Conduction ◽  
Carboxylate Ligand ◽  
High Proton ◽  
Conduction Behavior ◽  
Lanthanide Metal

Two novel 12-connected 3D porous lanthanide–organic frameworks have been synthesized by the reaction of bipyridine-carboxylate ligand bpydbH2 and lanthanide metal ions. Both of them show a high proton conduction behavior as well as their composite membranes.

High Proton Conduction at above 100 °C Mediated by Hydrogen Bonding in a Lanthanide Metal–Organic Framework

2014 ◽  
Vol 136 (35) ◽  
pp. 12444-12449 ◽  
Author(s):  
Qun Tang ◽  
Yiwei Liu ◽  
Shuxia Liu ◽  
Danfeng He ◽  
Jun Miao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

Assembly of three coordination polymers based on a sulfonic–carboxylic ligand showing high proton conductivity

2015 ◽  
Vol 44 (3) ◽  
pp. 948-954 ◽  
Author(s):  
Shu-Na Zhao ◽  
Xue-Zhi Song ◽  
Min Zhu ◽  
Xing Meng ◽  
Lan-Lan Wu ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Coordination Polymers ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Conduction Behavior

Three MOFs with different structures all exhibit proton conduction behavior, especially for the Cu compound with a proton conductivity of 3.46 × 10−3 S cm−1 at 368 K and 95% RH.

Metal in situ surface functionalization of polymer-grafted-carbon nanotube composite membranes for fast efficient nanofiltration

2017 ◽  
Vol 5 (2) ◽  
pp. 583-592 ◽  
Author(s):  
Faizal Soyekwo ◽  
Qiugen Zhang ◽  
Runsheng Gao ◽  
Yan Qu ◽  
Ruixue Lv ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Carbon Nanotube ◽  
Metal Ions ◽  
Surface Functionalization ◽  
Heavy Metal Ions ◽  
Composite Membranes ◽  
Carbon Nanotube Composite

Metal in situ surface functionalized PEI-g-MWCNT membranes are facilely prepared for nanofiltration of heavy metal ions in solution with high fluxes.

Extended Rodlike Polyaromatic Receptors with Bent Tridentate Units Complexed to Lanthanide Metal Ions

2000 ◽  
Vol 39 (23) ◽  
pp. 5286-5298 ◽  
Author(s):  
Homayoun Nozary ◽  
Claude Piguet ◽  
Jean-Pierre Rivera ◽  
Paul Tissot ◽  
Gérald Bernardinelli ◽  
...  
Keyword(s):  
Metal Ions ◽  
Lanthanide Metal

Microporous lanthanide metal-organic frameworks

2012 ◽  
Vol 32 (2-4) ◽  
pp. 81-100 ◽  
Author(s):  
Yao Chen ◽  
Shengqian Ma
Keyword(s):  
Optical Properties ◽  
Metal Ions ◽  
Porous Materials ◽  
Chemical Sensing ◽  
Metal Organic Frameworks ◽  
Current Status ◽  
Multifunctional Materials ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Solvent Adsorption

AbstractMicroporous metal-organic frameworks (MOFs) based on lanthanide metal ions or clusters represent a group of porous materials, featuring interesting coordination, electronic, and optical properties. These attractive properties in combination with the porosity make microporous lanthanide MOFs (Ln-MOFs) hold the promise for various applications. This review is to provide an overview of the current status of the research in microporous Ln-MOFs, and highlight their potential as types of multifunctional materials for applications in gas/solvent adsorption and separation, luminescence and chemical sensing and catalysis.

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