scholarly journals Visible-light photoexcitation of pyridine surface complex, leading to selective dehydrogenative cross-coupling with cyclohexane

2018 ◽  
Vol 20 (45) ◽  
pp. 28375-28381 ◽  
Author(s):  
Shimpei Naniwa ◽  
Akanksha Tyagi ◽  
Akira Yamamoto ◽  
Hisao Yoshida
Keyword(s):  
Reaction Mechanism ◽  
Visible Light ◽  
Cross Coupling ◽  
Surface Complex ◽  
Unique Reaction

A pyridine–TiO2 LMCT complex is excited by visible light to achieve selective DCC with cyclohexane via a unique reaction mechanism.

Ligand-to-metal charge transfer of pyridine surface complex on TiO2 for selective dehydrogenative cross-coupling with benzene

2021 ◽  
Author(s):  
Shimpei Naniwa ◽  
Shinichiro Hishitani ◽  
Akira Yamamoto ◽  
Hisao Yoshida
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Cross Coupling ◽  
Light Irradiation ◽  
Surface Complex ◽  
Metal Charge ◽  
Metal Charge Transfer

Dehydrogenative cross-coupling (DCC) between pyridine and benzene proceeded selectively using TiO2 photocatalyst under visible light irradiation at optimized concentrations of the substrates. Visible light induces ligand-to-metal charge transfer (LMCT) between...

The Merger of CF3SO2Na and Palladium Catalysis to Enable Decarboxylative Cross-Coupling for the Synthesis of Aromatic Ketones under Room Temperature

2021 ◽  
Author(s):  
Pan Xie ◽  
Cheng Xue ◽  
Cancan Wang ◽  
Dongdong Du ◽  
Sanshan Shi
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Palladium Catalysis ◽  
Cross Coupling ◽  
Boronic Acids ◽  
Aromatic Ketones ◽  
Aryl Ketones ◽  
Oxocarboxylic Acids

A CF3SO2Na/Pd(OAc)2 co-catalyzed strategy is developed to produce aryl ketones via visible-light-induced decarboxylative cross-coupling of α-oxocarboxylic acids and aryl boronic acids. This process was perfomed under air at room temperature,...

A Visible‐Light‐Harvesting Covalent Organic Framework Bearing Single Nickel Sites as a Highly Efficient Sulfur‐Carbon Cross‐Coupling Dual Catalyst

2021 ◽  
Author(s):  
Pascal van der Voort ◽  
Hui Chen ◽  
Wanlu Liu ◽  
Andreas Laemont ◽  
Chidharth Krishnaraj ◽  
...  
Keyword(s):  
Visible Light ◽  
Light Harvesting ◽  
Cross Coupling ◽  
Covalent Organic Framework ◽  
Highly Efficient ◽  
Organic Framework

A novel sucrose chelated visible-light sensitive AFO NPs: preparation, characterization, photocatalytic activity, and reaction mechanism

2021 ◽  
Author(s):  
Harminder Singh ◽  
Jaspreet Kaur Rajput ◽  
Nazuk Dogra ◽  
Geetika Jain ◽  
Ankush Gupta ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Reaction Mechanism ◽  
Visible Light

D–π–A-type triphenylamine dye covalent-functionalized g-C3N4 for highly efficient photocatalytic hydrogen evolution

2020 ◽  
Vol 10 (6) ◽  
pp. 1609-1618 ◽  
Author(s):  
Chao Zhang ◽  
Jiandong Liu ◽  
Xingliang Liu ◽  
Shiai Xu
Keyword(s):  
Reaction Mechanism ◽  
Visible Light ◽  
Hydrogen Evolution ◽  
Visible Light Irradiation ◽  
Photocatalytic Performance ◽  
Light Irradiation ◽  
Photocatalytic Hydrogen Evolution ◽  
Highly Efficient

Reaction mechanism for the higher photocatalytic performance of H2 production of g-C3N4NSs/TC1 under visible light irradiation (λ ≥ 400 nm).

Direct Access to α‐Aminosilanes Enabled by Visible‐Light‐Mediated Multicomponent Radical Cross‐Coupling

2021 ◽  
Author(s):  
Xiaoye Yu ◽  
Constantin Gabriel Daniliuc ◽  
Fatmah Ali Alasmary ◽  
Armido Studer
Keyword(s):  
Visible Light ◽  
Cross Coupling ◽  
Direct Access

Visible-Light-Promoted Cross-Coupling of N-Alkylpyridinium Salts and Nitrostyrenes

2021 ◽  
Author(s):  
Branislav Ferko ◽  
Michaela Marčeková ◽  
Katarína Ráchel Detková ◽  
Jana Doháňošová ◽  
Dušan Berkeš ◽  
...  
Keyword(s):  
Visible Light ◽  
Cross Coupling
Sign in / Sign up

Export Citation Format

Share Document