scholarly journals Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes

2018 ◽  
Vol 47 (31) ◽  
pp. 10671-10684 ◽  
Author(s):  
Fady Nahra ◽  
Kristof Van Hecke ◽  
Alan R. Kennedy ◽  
David J. Nelson
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Heterocyclic Carbenes ◽  
Coinage Metal

The coordination chemistry of selenoureas derived from N-heterocyclic carbenes with copper and silver is explored, and compared to previous work with gold.

scholarly journals N-Heterocyclic carbenes on close-packed coinage metal surfaces: bis-carbene metal adatom bonding scheme of monolayer films on Au, Ag and Cu

2017 ◽  
Vol 8 (12) ◽  
pp. 8301-8308 ◽  
Author(s):  
Li Jiang ◽  
Bodong Zhang ◽  
Guillaume Médard ◽  
Ari Paavo Seitsonen ◽  
Felix Haag ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Metal Surfaces ◽  
Heterocyclic Carbenes ◽  
Solid Surfaces ◽  
Monolayer Films ◽  
Coinage Metal ◽  
Bonding Scheme ◽  
Group 11 Metals

N-Heterocyclic carbenes wet the solid surfaces of group 11 metals with energetically favourable electron donating biscarbene metal complexes.

Non-covalent interactions in coinage metal complexes of 1,2,4-triazole-based N-heterocyclic carbenes

2014 ◽  
Vol 43 (41) ◽  
pp. 15465-15474 ◽  
Author(s):  
Jan Turek ◽  
Illia Panov ◽  
Petr Švec ◽  
Zdeňka Růžičková ◽  
Aleš Růžička
Keyword(s):  
Metal Complexes ◽  
Heterocyclic Carbenes ◽  
Coinage Metal ◽  
Complete Series ◽  
Non Covalent Interactions ◽  
Covalent Interactions

Non-covalent interactions were revealed in the complete series of coinage metal complexes of the type (NHC)MX (M = Cu, Ag, Au; X = Cl, Br, I) bearing 1,2,4-triazole based NHCs.

Coinage Metal Complexes of Bis-Alkynyl-Functionalized N-Heterocyclic Carbenes: Reactivity, Photophysical Properties, and Quantum Chemical Investigations

2017 ◽  
Vol 23 (7) ◽  
pp. 1591-1603 ◽  
Author(s):  
Claude Kiefer ◽  
Sebastian Bestgen ◽  
Michael T. Gamer ◽  
Michael Kühn ◽  
Sergei Lebedkin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Quantum Chemical ◽  
Photophysical Properties ◽  
Heterocyclic Carbenes ◽  
Coinage Metal

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

scholarly journals Expedient synthesis of N-Oxy-Heterocyclic Carbenes (NOHC) ligands and metal complexes using mechanochemistry

2021 ◽  
pp. 121914
Author(s):  
Aneta Wróblewska ◽  
Gaëtan Lauriol ◽  
Grzegorz Mlostoń ◽  
Xavier Bantreil ◽  
Frédéric Lamaty
Keyword(s):  
Metal Complexes ◽  
Heterocyclic Carbenes

Influence of anellation in N-heterocyclic carbenes: Novel quinoxaline-anellated NHCs trapped as transition metal complexes

2006 ◽  
pp. 640 ◽  
Author(s):  
Shanmuganathan Saravanakumar ◽  
Markus K. Kindermann ◽  
Joachim Heinicke ◽  
Martin Köckerling
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Heterocyclic Carbenes
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