A metal–organic-framework approach to engineer hollow bimetal oxide microspheres towards enhanced electrochemical performances of lithium storage

2019 ◽  
Vol 48 (6) ◽  
pp. 2019-2027 ◽  
Author(s):  
Weiwei Sun ◽  
Si Chen ◽  
Yong Wang

A MOF-derived approach is used to fabricate a Fe–Mn–O/C hollow microsphere anode, which delivers excellent electrochemical performance for lithium-ion batteries.

2017 ◽  
Vol 5 (46) ◽  
pp. 24269-24274 ◽  
Author(s):  
Yongzhe Wang ◽  
Mingguang Kong ◽  
Ziwei Liu ◽  
Chucheng Lin ◽  
Yi Zeng

Multilayered Co3O4/NiO/C electrodes with a ball-in-ball hollow morphology are employed in lithium-ion batteries and deliver an excellent rate capacity of 421 mA h g−1 at 4 A g−1 and a high capacity of 776 mA h g−1 over 1000 cycles at 1 A g−1.


2016 ◽  
Vol 4 (32) ◽  
pp. 12434-12441 ◽  
Author(s):  
Guoliang Xia ◽  
Dong Liu ◽  
Fangcai Zheng ◽  
Yang Yang ◽  
Jianwei Su ◽  
...  

Porous MoO2@C nanocomposite was synthesized through the direct pyrolysis of NENU-5 and showed an excellent electrochemical performance (1442 mA h g−1 at 0.1 A g−1 for 50 cycles and 443.8 mA h g−1 at 1 A g−1 for 850 cycles) when tested as anode materials for LIBs.


2017 ◽  
Vol 46 (45) ◽  
pp. 15947-15953 ◽  
Author(s):  
Ming Zhong ◽  
Dong-Hui Yang ◽  
Ling-Jun Kong ◽  
Wei Shuang ◽  
Ying-Hui Zhang ◽  
...  

The morphology and electrochemical performance of the as-prepared Co3O4–CoFe2O4 composites from bimetallic metal–organic framework precursors depend greatly on the initial Fe3+/Co2+ molar ratio.


2021 ◽  
Author(s):  
Dongjian Li ◽  
Hongtao Guo ◽  
Shaohua Jiang ◽  
Guilin Zeng ◽  
Wei Zhou ◽  
...  

Mg–Zr-Ti co-modified NCM with excellent electrochemical performance is obtained by a solid-state method.


CrystEngComm ◽  
2020 ◽  
Vol 22 (8) ◽  
pp. 1340-1345 ◽  
Author(s):  
Xiya Yang ◽  
Peipei Zhu ◽  
Xiaoliang Ma ◽  
Wenjing Li ◽  
Zenglong Tan ◽  
...  

A new porous POM supported graphite-like MOF (Cu-POM) as a LIB anode material was designed and synthesized, and its lithium storage mechanism was explored using impedance spectra.


2015 ◽  
Vol 3 (35) ◽  
pp. 18036-18044 ◽  
Author(s):  
Qinghua Tian ◽  
Yang Tian ◽  
Zhengxi Zhang ◽  
Li Yang ◽  
Shin-ichi Hirano

The as-prepared SnO2@DSC exhibits excellent electrochemical performance due to the double-shelled support and confined void strategy.


NANO ◽  
2019 ◽  
Vol 14 (07) ◽  
pp. 1950082 ◽  
Author(s):  
Jianglin Xu ◽  
Yaping Zhu ◽  
Yan Sun ◽  
Anjian Xie

In this report, the porous Fe3O4/C nanocomposites were successfully synthesized by using ferrocene as raw material and dilute nitric acid as solvent via extremely convenient and low-cost one-step calcining method. The formation of porous structure resulted from the aggregation and assembly of numerous nanoparticles. The experimental results show that the crystallinities, morphologies and electrochemical performance of samples were affected by the calcining temperature and carbon content. As an anode for lithium-ion batteries (LIBs), the Fe3O4/C nanocomposites obtained at calcination temperature of 500∘C (Fe3O4/C-a500) exhibited remarkable initial specific discharge capacity of 1418[Formula: see text]mA[Formula: see text]h g[Formula: see text] and a reversible capacity retention of 721[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text] after 100 cycles at the current density of 100[Formula: see text]mA[Formula: see text]g[Formula: see text]. The excellent properties can be attributed to the high theoretical capacity of Fe3O4, the high conductivity of carbon and especially the porous structure, which offered more sites for the storage and insertion of Li ions. Even at the current density of 1000[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text], the reversible capacity of Fe3O4/C-a500 can be up to 291[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text], indicating the prepared typical nanocomposite presented excellent electrochemical performances and lithium storage capacity, which may be a promising candidate as the anode material for LIBs.


2018 ◽  
Vol 6 (46) ◽  
pp. 23819-23827 ◽  
Author(s):  
Hailong Yue ◽  
Guangming Wang ◽  
Rencheng Jin ◽  
Qingyao Wang ◽  
Yuming Cui ◽  
...  

Sulfur-doped amorphous NiMoO4 on crystalline Fe2O3 nanosheets has been fabricated, which demonstrates excellent electrochemical performance as the anode for lithium ion batteries.


Nanoscale ◽  
2015 ◽  
Vol 7 (4) ◽  
pp. 1446-1453 ◽  
Author(s):  
Yuanjuan Bai ◽  
Huijuan Zhang ◽  
Xiao Li ◽  
Li Liu ◽  
Haitao Xu ◽  
...  

A novel peapod-like Ni2P/C nanocomposite is designed and synthesized using NiNH4PO4H2O nanorod sacrificial templates. The nanocomposite exhibits high activity and stability for the hydrogen evolution reaction and an excellent electrochemical performance for use in lithium ion batteries.


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