Heterogeneous non-mercury catalysts for acetylene hydrochlorination: progress, challenges, and opportunities

2018 ◽  
Vol 20 (11) ◽  
pp. 2412-2427 ◽  
Author(s):  
Jiawei Zhong ◽  
Yunpeng Xu ◽  
Zhongmin Liu
Keyword(s):  
Green Chemistry ◽  
Vinyl Chloride ◽  
Polyvinyl Chloride ◽  
Mercuric Chloride ◽  
Vinyl Chloride Monomer ◽  
Acetylene Hydrochlorination ◽  
Challenges And Opportunities

The replacement of mercuric chloride with non-mercury catalysts in acetylene hydrochlorination for the production of a vinyl chloride monomer, a precursor to polyvinyl chloride, would meet the requirements of green chemistry and have a great significance in the industrial field.

scholarly journals Acetylene hydrochlorination using Au/carbon: a journey towards single site catalysis

2017 ◽  
Vol 53 (86) ◽  
pp. 11733-11746 ◽  
Author(s):  
Grazia Malta ◽  
Simon J. Freakley ◽  
Simon A. Kondrat ◽  
Graham J. Hutchings
Keyword(s):  
Environmental Impact ◽  
Vinyl Chloride ◽  
Mercuric Chloride ◽  
Large Scale ◽  
Industrial Process ◽  
Single Site ◽  
Vinyl Chloride Monomer ◽  
Acetylene Hydrochlorination

The replacement of mercuric chloride in the production of vinyl chloride monomer, a precursor to PVC, would greatly reduce the environmental impact of this large scale industrial process.

scholarly journals Non-mercury catalytic acetylene hydrochlorination over Bi/CNTs catalysts for vinyl chloride monomer production

2020 ◽  
Vol 9 (6) ◽  
pp. 14961-14968
Author(s):  
Lizhen Lian ◽  
Lu Wang ◽  
Haijun Yan ◽  
Shahid Ali ◽  
Jide Wang ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Vinyl Chloride Monomer ◽  
Acetylene Hydrochlorination

Mortality and cancer morbidity in workers exposed to low levels of vinyl chloride monomer at a polyvinyl chloride processing plant

1990 ◽  
Vol 17 (5) ◽  
pp. 553-565 ◽  
Author(s):  
Lars Hagmar ◽  
Bengt Kesson ◽  
Jsrn Nielsen ◽  
Christina Andersson ◽  
Katarina Lindan ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Polyvinyl Chloride ◽  
Processing Plant ◽  
Vinyl Chloride Monomer ◽  
Cancer Morbidity ◽  
Low Levels

Mortality from liver disease among italian vinyl chloride monomer/polyvinyl chloride manufacturers

1990 ◽  
Vol 17 (2) ◽  
pp. 155-161 ◽  
Author(s):  
R. Pirastu ◽  
P. Comba ◽  
A. Reggiani ◽  
V. Foa ◽  
A. Masina ◽  
...  
Keyword(s):  
Liver Disease ◽  
Vinyl Chloride ◽  
Polyvinyl Chloride ◽  
Vinyl Chloride Monomer

A Comprehensive Analysis of Plausible Genotoxic Covariates Among Workers of a Polyvinyl Chloride Plant Exposed to Vinyl Chloride Monomer

2012 ◽  
Vol 64 (4) ◽  
pp. 652-658 ◽  
Author(s):  
Alagamuthu Karthick Kumar ◽  
Vellingiri Balachandar ◽  
Meyyazhagan Arun ◽  
Shafi Ahammed Khan Mustaq Ahamed ◽  
Shanmugam Suresh Kumar ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Polyvinyl Chloride ◽  
Comprehensive Analysis ◽  
Vinyl Chloride Monomer

Synthesis of a vinyl chloride monomer via acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

2020 ◽  
Vol 10 (11) ◽  
pp. 3552-3560 ◽  
Author(s):  
Ming Cai ◽  
Haiyang Zhang ◽  
Baochang Man ◽  
Jian Li ◽  
Linfeng Li ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Vinyl Chloride Monomer ◽  
Complex Catalyst ◽  
Acetylene Hydrochlorination ◽  
Carbene Complex

Delocalisation and transfer of electrons in the formed IPr–(Ru) synergistically yields a significant improvement in activity with respect to its counterpart.

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