Efficient ethylene copolymerization with polar monomers using palladium anilinonaphthoquinone catalysts

Lin Ding; Hailong Cheng; Yanqing Li; Ryo Tanaka; Takeshi Shiono; Zhengguo Cai

doi:10.1039/c8py01292j

Efficient ethylene copolymerization with polar monomers using palladium anilinonaphthoquinone catalysts

Polymer Chemistry ◽

10.1039/c8py01292j ◽

2018 ◽

Vol 9 (45) ◽

pp. 5476-5482 ◽

Cited By ~ 9

Author(s):

Lin Ding ◽

Hailong Cheng ◽

Yanqing Li ◽

Ryo Tanaka ◽

Takeshi Shiono ◽

...

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Polar Monomers

Copolymerizations of ethylene with methyl acrylate (MA) and 5-norbornen-2-yl acetate (NBAC) were explored using anilinonaphthoquinone-ligated palladium catalysts.

The leaching and re-deposition of metal species from and onto conventional supported palladium catalysts in the Heck reaction of iodobenzene and methyl acrylate in N-methylpyrrolidone

Journal of Molecular Catalysis A Chemical ◽

10.1016/s1381-1169(01)00436-8 ◽

2002 ◽

Vol 180 (1-2) ◽

pp. 211-219 ◽

Cited By ~ 134

Author(s):

Fengyu Zhao ◽

Masayuki Shirai ◽

Yutaka Ikushima ◽

Masahiko Arai

Keyword(s):

Methyl Acrylate ◽

Heck Reaction ◽

Palladium Catalysts ◽

Metal Species ◽

Supported Palladium Catalysts ◽

Supported Palladium

Substituent Effects of the Backbone in α-Diimine Palladium Catalysts on Homo- and Copolymerization of Ethylene with Methyl Acrylate

Organometallics ◽

10.1021/om300380b ◽

2012 ◽

Vol 31 (17) ◽

pp. 6054-6062 ◽

Cited By ~ 104

Author(s):

Lihua Guo ◽

Haiyang Gao ◽

Qirui Guan ◽

Haibin Hu ◽

Juean Deng ◽

...

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Substituent Effects

Bis(N-acylated imidazolin-2-imine) nickel catalyzed norbornene copolymerization with methyl acrylate

Polymer Chemistry ◽

10.1039/d0py00857e ◽

2020 ◽

Vol 11 (34) ◽

pp. 5542-5547

Author(s):

Yanqing Li ◽

Hu Zhang ◽

Ru Xiao ◽

Zhengguo Cai

Keyword(s):

Methyl Acrylate ◽

Nickel Complexes ◽

Polar Monomers ◽

Norbornene Polymerization

We herein report the synthesis of novel bis(N-acylated imidazolin-2-imine) nickel complexes for norbornene polymerization and copolymerization with polar monomers.

Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using “Sandwich” Diimine Palladium Catalysts

ACS Catalysis ◽

10.1021/cs5016029 ◽

2014 ◽

Vol 5 (1) ◽

pp. 456-464 ◽

Cited By ~ 100

Author(s):

Kate E. Allen ◽

Jesús Campos ◽

Olafs Daugulis ◽

Maurice Brookhart

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Living Polymerization ◽

Ethylene Methyl Acrylate

Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts

Chemical Science ◽

10.1039/c5sc03361f ◽

2016 ◽

Vol 7 (1) ◽

pp. 737-744 ◽

Cited By ~ 43

Author(s):

Yusuke Mitsushige ◽

Brad P. Carrow ◽

Shingo Ito ◽

Kyoko Nozaki

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Ethylene Methyl Acrylate

A new series of palladium catalysts ligated by a chelating bisphosphine monoxide bearing diarylphosphino groups (aryl-BPMO) exhibits markedly higher reactivity for ethylene/methyl acrylate copolymerisation.

Copolymerization of ethylene and methyl acrylate by palladium catalysts bearing IzQO ligands containing methoxyethyl ether moieties and salt effects for polymerization

Polymer Journal ◽

10.1038/s41428-021-00500-3 ◽

2021 ◽

Author(s):

Shumpei Akita ◽

Kyoko Nozaki

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Salt Effects

Effects of chemical modification of supports on properties of tertiary amino resin dispersed palladium catalysts for the hydrogenation of methyl acrylate

Makromolekulare Chemie Macromolecular Symposia ◽

10.1002/masy.19920590110 ◽

1992 ◽

Vol 59 (1) ◽

pp. 99-111

Author(s):

Chunfu Chen ◽

Juntan Sun ◽

Hong Li ◽

Binglin He

Keyword(s):

Chemical Modification ◽

Methyl Acrylate ◽

Palladium Catalysts ◽

Amino Resin ◽

Tertiary Amino

Homo- and copolymerization of norbornene using tridentate IzQO palladium catalysts with dimethylaminoethyl as a side arm

Polymer Chemistry ◽

10.1039/d1py00699a ◽

2021 ◽

Author(s):

Jie Dong ◽

Baiquan Wang

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Palladium Catalysts ◽

Olefin Polymerization ◽

Heterocyclic Carbenes ◽

Late Transition Metal ◽

Polar Monomers ◽

Late Transition

Late-transition metal complexes containing N-heterocyclic carbenes (NHCs) are still limited in the field of olefin polymerization, especially in the copolymerization of olefins with polar monomers. In this contribution, a series...

Indole-bridged bisphosphine-monoxide palladium catalysts for ethylene polymerization and copolymerization with polar monomers

Polymer Chemistry ◽

10.1039/d0py00100g ◽

2020 ◽

Vol 11 (15) ◽

pp. 2740-2748 ◽

Cited By ~ 3

Author(s):

Kangkang Li ◽

Junhao Ye ◽

Zhen Wang ◽

Hongliang Mu ◽

Zhongbao Jian

Keyword(s):

Palladium Catalysts ◽

Ethylene Polymerization ◽

Molecular Weights ◽

Polar Monomers

Novel indole-based C–N-bridged bisphosphine-monoxide palladium catalysts enable ethylene polymerization with completely different activities and molecular weights and copolymerization with polar comonomers.

Sterically very bulky aliphatic/aromatic phosphine-sulfonate palladium catalysts for ethylene polymerization and copolymerization with polar monomers

Polymer Chemistry ◽

10.1039/c8py01568f ◽

2019 ◽

Vol 10 (4) ◽

pp. 546-554 ◽

Cited By ~ 12

Author(s):

Jian Xia ◽

Yixin Zhang ◽

Xiaoqiang Hu ◽

Xin Ma ◽

Lei Cui ◽

...

Keyword(s):

Molecular Weight ◽

High Molecular Weight ◽

Palladium Catalysts ◽

Ethylene Polymerization ◽

Polar Monomers

Copolymerization of ethylene and polar monomers with significantly high molecular weight and activity was achieved using bulky aliphatic/aromatic phosphine-sulfonate palladium catalysts.