scholarly journals Black Si-doped TiO2 nanotube photoanode for high-efficiency photoelectrochemical water splitting

RSC Advances ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 5652-5660 ◽  
Author(s):  
Zhenbiao Dong ◽  
Dongyan Ding ◽  
Ting Li ◽  
Congqin Ning

Black Si-doped TiO2 (Ti–Si–O) nanotubes were fabricated through Zn metal reduction of the Ti–Si–O nanotubes on Ti–Si alloy in an argon atmosphere.

2014 ◽  
Vol 2 (23) ◽  
pp. 8612-8616 ◽  
Author(s):  
Houlei Cui ◽  
Wei Zhao ◽  
Chongyin Yang ◽  
Hao Yin ◽  
Tianquan Lin ◽  
...  

Black titania nanotube arrays are prepared for the first time, which exhibit an excellent photoelectrochemical water-splitting performance.


2015 ◽  
Vol 3 (2) ◽  
pp. 699-705 ◽  
Author(s):  
Hui Li ◽  
Jiangqiong Chen ◽  
Zhengbin Xia ◽  
Junheng Xing

Bulk abundant Ti3+ self-doped TiO2 nanotube arrays are prepared by a microwave-assisted chemical reduction method with NaBH4.


2019 ◽  
Vol 12 (06) ◽  
pp. 1940004
Author(s):  
Dawei Si ◽  
Zhenbiao Dong ◽  
Ting Li ◽  
Dongyan Ding ◽  
Congqin Ning

TiO2 is a promising photocatalyst in the reaction of water splitting for hydrogen. Here, we used NaBH4 reduction reaction to introduce [Formula: see text]/VO defect states into Si-doped TiO2 nanotubes and investigated the photoelectrochemical water splitting properties. It was found that the photocatalytic activity was improved through NaBH4 reduction because of the existence of [Formula: see text]/VO. The defect states ([Formula: see text]/VO) could play a role of capture trap and accelerate the separation of photogenerated electrons and holes. The photocurrent density of the Si-doped TiO2 nanotubes reduced for 3[Formula: see text]h was 1.5[Formula: see text]mA/cm2 compared to 0.7[Formula: see text]mA/cm2 of the unreduced nanotubes. The conversion efficiency was 0.7%, which was almost 4 times than that of pure TiO2. On the other hand, reduction for a long time would generate excess defect states and thus cause the decrease of photocurrent density. Excess defect states could act as the recombination centers of photogenerated electrons and holes.


2019 ◽  
Vol 7 (14) ◽  
pp. 8061-8072 ◽  
Author(s):  
Erhuan Zhang ◽  
Jia Liu ◽  
Muwei Ji ◽  
Hongzhi Wang ◽  
Xiaodong Wan ◽  
...  

Construction of hollow anisotropic semiconductor nanostructures that possess excellent crystallinity, flexibly tunable structure/morphology and aqueous dispersity is of special interest for photoelectrochemical (PEC) water splitting


2021 ◽  
Author(s):  
Dong Qiu ◽  
Chengli He ◽  
Yuxuan Lu ◽  
Qiaodan Li ◽  
Yang Chen ◽  
...  

Photoelectrochemical water splitting is an excellent strategy for hydrogen generation, and it is pivotal to develop photoanodes with proficient sunlight harvesting, rapid charge separation, and enhanced electron injection efficiency. In...


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