Ionic liquids as an efficient medium for the mechanochemical synthesis of α-AlH3 nano-composites

Aluminum hydride (AlH3) is one of the most promising hydrogen storage materials that has a high theoretical hydrogen storage capacity (10.08 wt%) and relatively low dehydriding temperature (100–200 °C).

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Recent advances on the thermal destabilization of Mg-based hydrogen storage materials

RSC Advances ◽

10.1039/c8ra05596c ◽

2019 ◽

Vol 9 (1) ◽

pp. 408-428 ◽

Cited By ~ 20

Author(s):

Jianfeng Zhang ◽

Zhinian Li ◽

Yuanfang Wu ◽

Xiumei Guo ◽

Jianhua Ye ◽

...

Keyword(s):

Hydrogen Storage ◽

Storage Capacity ◽

Magnesium Hydride ◽

Hydrogen Storage Materials ◽

Hydrogen Storage Capacity ◽

High Hydrogen ◽

Storage Materials ◽

Recent Advances

Magnesium hydride and its compounds have a high hydrogen storage capacity and are inexpensive, and thus have been considered as one of the most promising hydrogen storage materials for on-board applications.

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Investigations of AB5-type hydrogen storage materials with enhanced hydrogen storage capacity

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2011.02.111 ◽

2011 ◽

Vol 36 (12) ◽

pp. 7114-7121 ◽

Cited By ~ 14

Author(s):

Sumita Srivastava ◽

R.K. Upadhyaya

Keyword(s):

Hydrogen Storage ◽

Storage Capacity ◽

Hydrogen Storage Materials ◽

Hydrogen Storage Capacity ◽

Storage Materials

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Using Ball Milling for Modification of the Hydrogenation/Dehydrogenation Process in Magnesium-Based Hydrogen Storage Materials: An Overview

Metals ◽

10.3390/met9070768 ◽

2019 ◽

Vol 9 (7) ◽

pp. 768 ◽

Cited By ~ 9

Author(s):

Jinzhe Lyu ◽

Andrey Lider ◽

Viktor Kudiiarov

Keyword(s):

Hydrogen Storage ◽

Ball Milling ◽

Hydrogen Absorption ◽

Storage Capacity ◽

Low Cost ◽

Temperature Limit ◽

Computer Design ◽

Hydrogen Storage Materials ◽

Hydrogen Storage Capacity ◽

Storage Materials

Magnesium-based hydrogen storage materials are considered to be one of the most promising solid-state hydrogen storage materials due to their large hydrogen storage capacity and low cost. However, slow hydrogen absorption/desorption rate and excessive hydrogen absorption/desorption temperature limit the application of magnesium-based hydrogen storage materials. The present paper reviews recent progress in improving the hydrogen storage properties by element substitution and additives. Ball milling is the promising technology for preparing magnesium-based hydrogen storage materials. The research and development of approaches for modifying magnesium-based hydrogen storage materials prepared by ball milling is systematically expounded. It is concluded that ball milling can significantly improve the kinetic and electrochemical properties of magnesium-based hydrogen storage materials and increase the hydrogen storage capacity. In the future, the research of magnesium-based hydrogen storage materials should be developed in terms of hydrogen storage mechanism, computer design of materials and development of a more optimized catalytic system.

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Improvement of hydrogen storage characteristcs of MgH2 with flake Ni nano-catalyst composite

Dalton Transactions ◽

10.1039/d0dt03627g ◽

2021 ◽

Author(s):

xinglin Yang ◽

Quanhui Hou ◽

libing Yu ◽

Jiaqi Zhang

Keyword(s):

Hydrogen Storage ◽

Storage Capacity ◽

Low Cost ◽

Magnesium Hydride ◽

Hydrogen Storage Materials ◽

Hydrogen Storage Capacity ◽

High Hydrogen ◽

Storage Materials ◽

Nano Catalyst ◽

Slow Kinetic

Magnesium hydride (MgH2) is considered as one of the most promising hydrogen storage materials due to its safety, low cost and high hydrogen storage capacity. However, its slow kinetic performance...

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First-Principles Study on the Hydrogen Storage of Sandwich-Type Dimetallocenes

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.677.149 ◽

2013 ◽

Vol 677 ◽

pp. 149-152

Author(s):

Bo An ◽

Hai Yan Zhu

Keyword(s):

Hydrogen Storage ◽

First Principles ◽

Storage Capacity ◽

High Capacity ◽

First Principles Calculation ◽

Hydrogen Storage Materials ◽

Ambient Conditions ◽

Hydrogen Storage Capacity ◽

Hydrogen Molecules ◽

Sandwich Type

The paper mainly focuses on the ability of absorbing hydrogen molecule of the dimetallocene (C5H5)2TM2(TM=Ti/Zn/Cu/Ni) based on the first-principles calculation. The result indicates that these compounds can adsorb up to eight hydrogen molecules, the binding energy is 0.596eV/H2 for Cp2Ti2, 0.802eV/H2 for Cp2Zn2, 0.422eV/H2 for Cp2Cu2 and 0.182eV/H2 for Cp2Ni2 respectively. The corresponding gravimetric hydrogen-storage capacity is 7.1wt% for Cp2Ti2, 6.2wt% for Cp2Zn2, 6.3wt% for Cp2Cu2 and 6.5wt% for Cp2Ni2 respectively. These sandwich-type organometallocenes proposed in this work are favorable for reversible adsorption and desorption of hydrogen under ambient conditions. These predictions will likely provide a new route for developing novel high-capacity hydrogen-storage materials.

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