High-performance lithium–organic batteries by achieving 16 lithium storage in poly(imine-anthraquinone)

2019 ◽  
Vol 7 (5) ◽  
pp. 2368-2375 ◽  
Author(s):  
Zengming Man ◽  
Peng Li ◽  
Dong Zhou ◽  
Rui Zang ◽  
Shijian Wang ◽  
...  

The Li/PIAQ cell exhibits excellent electrochemical performances with a 16 Li-storage mechanism based on DFT calculations and experimental investigations.

Nano Energy ◽  
2018 ◽  
Vol 50 ◽  
pp. 25-34 ◽  
Author(s):  
Songjie Cao ◽  
Zhe Xue ◽  
Chengwu Yang ◽  
Jiaqian Qin ◽  
Long Zhang ◽  
...  

Carbon ◽  
2020 ◽  
Vol 166 ◽  
pp. 26-35 ◽  
Author(s):  
Sen Gao ◽  
Qiuyi Jiang ◽  
Yu Shi ◽  
Hyehee Kim ◽  
Ahmed Busnaina ◽  
...  

2019 ◽  
Vol 7 (13) ◽  
pp. 7553-7564 ◽  
Author(s):  
Zhenyou Li ◽  
Alexander Ottmann ◽  
Qing Sun ◽  
Anne K. Kast ◽  
Kai Wang ◽  
...  

Downsizing the building blocks of hierarchical structure towards molecular layer level helps to improve the Li storage performance significantly.


2019 ◽  
Vol 12 (7) ◽  
pp. 2286-2297 ◽  
Author(s):  
Wenwu Li ◽  
Xinwei Li ◽  
Jun Liao ◽  
Bote Zhao ◽  
Lei Zhang ◽  
...  

Cation-disordered Zn(Cu)–Si–P family materials demonstrate better Li-storage performance than the cation-ordered ZnSiP2 phase due largely to faster electronic and ionic conductivity and better tolerance to volume change during cycling, as confirmed by DFT calculations and experimental measurements.


2016 ◽  
Vol 4 (28) ◽  
pp. 10974-10985 ◽  
Author(s):  
Gongzheng Yang ◽  
Shuoyu Li ◽  
Mingmei Wu ◽  
Chengxin Wang

We report the facile preparation of ultrathin Zn3(OH)2V2O7·2H2O nanosheets and for the first time in detail investigate their lithium-storage mechanism.


2015 ◽  
Vol 3 (40) ◽  
pp. 20389-20398 ◽  
Author(s):  
Changzhou Yuan ◽  
Hui Cao ◽  
Siqi Zhu ◽  
Hui Hua ◽  
Linrui Hou

Core–shell ZnO/ZnFe2O4@C nanospheres were rationally fabricated and exhibited exceptional electrochemical Li-storage performance for next-generation Li-ion batteries.


2016 ◽  
Vol 4 (22) ◽  
pp. 8762-8768 ◽  
Author(s):  
Weixin Song ◽  
Jun Chen ◽  
Xiaobo Ji ◽  
Xuemei Zhang ◽  
Fang Xie ◽  
...  

A dandelion-shaped TiO2/few layer graphene composite presents ultrahigh electrochemical properties for Li storage due to the graphene boundary-involved triphase interfacial storage mechanism.


2019 ◽  
Vol 7 (26) ◽  
pp. 15621-15626 ◽  
Author(s):  
Eunjun Park ◽  
Yeong Eun Kim ◽  
Juhye Song ◽  
Min-Sik Park ◽  
Hansu Kim

By synergetic effect with unique microstructure and chemical composition, the biphasic Si/SiOx–SiO composites showed high performance Li storage characteristics.


2020 ◽  
Author(s):  
Jingwei Liu ◽  
Daixi Xie ◽  
Xiufang Xu ◽  
Luozhen Jiang ◽  
Rui Si ◽  
...  

Abstract Sn-based compounds with buffer matrixes possessing high theoretical capacity, low working voltage, and alleviation of the volume expansion of Sn are ideal materials for lithium storage. However, it is highly challenging to confine well-dispersed Sn within a lithium active matrix because low-melting-point Sn tends to agglomerate. Here, for the first time, we apply a metal-organic framework (MOF) chemistry between Sn-nodes and lithium active ligands to create two Sn-based MOFs comprising Sn2(dobdc) and Sn2(dobpdc) with extended ligands from H4dobdc (2,5-dioxido-1,4-benzenedicarboxylate acid) to H4dobpdc (4,4’-dioxidobiphenyl-3,3’-dicarboxylate acid) with molecule-level homodispersion of Sn in organic matrixes for lithium storage. The enhanced utilization of active sites and reaction kinetics are achieved by the isoreticular expansion of the organic linkers. The reversible formation of coordination bonds during lithium storage processes is first revealed by X-ray absorption fine structure characterization, providing an in-depth understanding of the lithium storage mechanism in coordination compounds.


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