Supramolecular chemistry of helical foldamers at the solid–liquid interface: self-assembled monolayers and anion recognition

2019 ◽  
Vol 55 (58) ◽  
pp. 8426-8429 ◽  
Author(s):  
Catherine Adam ◽  
Lara Faour ◽  
Valérie Bonnin ◽  
Tony Breton ◽  
Eric Levillain ◽  
...  
Keyword(s):  
Supramolecular Chemistry ◽  
Anion Recognition ◽  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Guest Binding ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid

Helical foldamers were incorporated in self-assembled monolayers that successfully transduce host–guest binding events.

Nanobubbles on a Very Flat Hydrophobic Surface Prepared by Self-Assembled Monolayers

2013 ◽  
Author(s):  
Takashi Nishiyama ◽  
Koji Takahashi ◽  
Yasuyuki Takata
Keyword(s):  
Heat Transfer ◽  
Gaseous Phase ◽  
Hydrophobic Surface ◽  
Bubble Nucleation ◽  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid

Boiling is one of the most effective heat transfer methods due to its high heat transfer coefficient. Therefore, boiling heat transfer plays a very important role for various applications in many technological and industrial areas. However, a very complex mechanism of boiling, especially bubble nucleation, is still not sufficiently understood. On the other hand, numerous experiments have revealed the existence of soft domains that called nanobubbles at the solid-liquid interface. In this study, to investigate the influence of the solid-liquid interface nanobubbles on the bubble nucleation, an atomic force microscope (AFM) is used to characterize the morphology of nanobubbles. In order to separate the effect of wettability of a solid surface from that of surface structure, a very flat hydrophobic surface was prepared. 1H,1H,2H,2H-Perfluoro-n-octylphosphonic acid (FOPA) formed the interface of hydrophobic self-assembled monolayers (SAMs). As the result of AFM measurement, many nanobubbles about 100 nm in diameter and 30 nm thick are observed at the interface of the FOPA surface and the pure water. In addition, to prove the existence of gaseous phase, the heat conductance measurement by time-domain thermoreflectance method (TDTR) was introduced. TDTR is an ultrafast optical pump probe technique well suited for thermal measurement of thin films. It enables to resolve the thermal conductivity of the thin film and the thermal conductance of the interface. If nanobubbles are the gaseous phase, the big change of interface heat thermal resistance will be seen and the TDTR signal should also change. The effectiveness of a TDTR to confirm the existence of nanobubbles is shown by the model simulation of TDTR. A clear difference is seen in TDTR signal by the existence of only 1 nm gaseous phase. After confirming the existence of nanobubbles by AFM measurement, it can be proved that the nanobubbles are truly gaseous phase of the TDTR measurement.

Rheology of self-assembled monolayers on solid-liquid interface oscillating at MHz frequency

2017 ◽  
Vol 55 (1) ◽  
pp. 16-21
Author(s):  
Minoru Yoshimoto ◽  
Keita Honda ◽  
Shigeru Kurosawa ◽  
Mutsuo Tanaka
Keyword(s):  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid

A Multivalent Hexapod: Conformational Dynamics of Six-Legged Molecules in Self-Assembled Monolayers at a Solid−Liquid Interface

ACS Nano ◽  
2009 ◽  
Vol 3 (4) ◽  
pp. 1016-1024 ◽  
Author(s):  
Hong Xu ◽  
Andrea Minoia ◽  
Željko Tomović ◽  
Roberto Lazzaroni ◽  
E. W. Meijer ◽  
...  
Keyword(s):  
Conformational Dynamics ◽  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid

Stress at the Solid−Liquid Interface of Self-Assembled Monolayers on Gold Investigated with a Nanomechanical Sensor

Langmuir ◽  
2000 ◽  
Vol 16 (25) ◽  
pp. 9694-9696 ◽  
Author(s):  
J. Fritz ◽  
M. K. Baller ◽  
H. P. Lang ◽  
T. Strunz ◽  
E. Meyer ◽  
...  
Keyword(s):  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid

Photoswitching Vertically Oriented Azobenzene Self-Assembled Monolayers at the Solid-Liquid Interface

2010 ◽  
Vol 16 (48) ◽  
pp. 14256-14260 ◽  
Author(s):  
David Bléger ◽  
Artur Ciesielski ◽  
Paolo Samorì ◽  
Stefan Hecht
Keyword(s):  
Liquid Interface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Solid Liquid Interface ◽  
Solid Liquid
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