Semi-bridging σ-silyls as Z-type ligands

2020 ◽  
Vol 56 (24) ◽  
pp. 3532-3535 ◽  
Author(s):  
Benjamin J. Frogley ◽  
Anthony F. Hill ◽  
Manab Sharma ◽  
Arup Sinha ◽  
Jas S. Ward
Keyword(s):  
Bimetallic Complexes ◽  
Silyl Groups ◽  
Group 10

The reactions of SiHPh(NCH2PPh2)2C6H4-1,2 with zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M2{μ-κ3-Si,P,P′-SiPh(CH2PPh2)2C6H4}2] (M = Ni, Pd, Pt) in which the M–M bond is unsymmetrically bridged by two σ-silyl groups.

Mono- and bimetallic complexes of the group 10 metals with N-heteroaryl phosphine ligands

2014 ◽  
Vol 758 ◽  
pp. 29-35 ◽  
Author(s):  
Christian Sarcher ◽  
Saeid Farsadpour ◽  
Leila Taghizadeh Ghoochany ◽  
Yu Sun ◽  
Werner R. Thiel ◽  
...  
Keyword(s):  
Phosphine Ligands ◽  
Bimetallic Complexes ◽  
Group 10 ◽  
Group 10 Metals

Influence of shift work on the formation of diseases of the digestive system

2020 ◽  
pp. 802-802
Author(s):  
E. F. Chernikova ◽  
M. M. Nekrasova ◽  
I. A. Potapova
Keyword(s):  
Shift Work ◽  
Police Officers ◽  
Digestive System ◽  
Traffic Police ◽  
Group 10

The analysis of the influence of the duration of shift work on the incidence of diseases of the digestive system (DDS) was carried out using the example of a group of traffic police officers. A significant increase in the incidence of DDS in the probation group 10 years or more compared to the group of up to 5 years indicates a high occupational conditionality of diseases of the digestive system.

Variable electronic effect of silyl groups attached to oxygen

1978 ◽  
Vol 43 (3) ◽  
pp. 746-752 ◽  
Author(s):  
Josef Pola ◽  
Václav Chvalovský
Keyword(s):  
Electronic Effect ◽  
Silyl Groups

Zero-valent ML2 complexes of group 10 metals supported by terphenyl phosphanes

2021 ◽  
Author(s):  
M. Trinidad Martín ◽  
Mario Marín ◽  
Raquel J. Rama ◽  
Eleuterio Alvarez González ◽  
Celia Maya ◽  
...  
Keyword(s):  
Coordination Numbers ◽  
Group 10 ◽  
Group 10 Metals

Bulky terphenyl phosphane ligands PMe2Ar’ (Ar’ = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in...

Synthesis of Stoichiometric SrTiO3 and Its Carrier Doping from Air-Stable Bimetallic Complexes

2021 ◽  
Vol 60 (3) ◽  
pp. 1277-1283
Author(s):  
Ebube E. Oyeka ◽  
Daichi Oka ◽  
Eunsang Kwon ◽  
Tomoteru Fukumura
Keyword(s):  
Bimetallic Complexes ◽  
Carrier Doping

scholarly journals Effects of 1.5 and 4.3 GHz microwave radiation on cognitive function and hippocampal tissue structure in Wistar rats

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ruiqing Zhu ◽  
Hui Wang ◽  
Xinping Xu ◽  
Li Zhao ◽  
Jing Zhang ◽  
...  
Keyword(s):  
Cognitive Function ◽  
Microwave Radiation ◽  
Structural Damage ◽  
Wistar Rats ◽  
Tissue Structure ◽  
Single Frequency ◽  
Hippocampal Tissue ◽  
Radiation Group ◽  
Morris Water Maze Task ◽  
Group 10

AbstractPrevious studies have shown that single-frequency microwave radiation can lead to cognitive decline in rats. However, few studies have focused on the combined effects of irradiation with different frequencies of microwaves. Our research aimed to investigate the effects of 1.5 GHz and 4.3 GHz microwave radiation, singly and in combination, on cognitive function and hippocampal tissue structure in rats. A total of 140 male Wistar rats were randomly divided into 4 groups: the S group (sham radiation group), L10 group (10 mW/cm2 1.5 GHz group), C10 group (10 mW/cm2 4.3 GHz band group) and LC10 group (10 mW/cm2 1.5 and 4.3 GHz multi-frequency radiation group). For 1–28 days after microwave radiation, we analyzed the average escape latency for the Morris water maze task, electroencephalograms, change in hippocampal tissue structure and ultrastructure, content of the Nissl body in the hippocampus, and activities of lactate dehydrogenase and succinate dehydrogenase. Compared to the S group, all exposure groups showed varying degrees of learning and memory decline and hippocampal structural damage. The results showed that 1.5 GHz and 4.3 GHz microwave radiation was able to induce cognitive impairment and hippocampal tissue damage in rats and combined radiation with both frequencies caused more serious injuries, but none of these damaging effects varied with microwave frequency.

scholarly journals Synthesis and characterisation of thin-film platinum disulfide and platinum sulfide

Nanoscale ◽  
2021 ◽  
Author(s):  
Conor Patrick Cullen ◽  
Cormac Ó Coileáin ◽  
John B McManus ◽  
Oliver Hartwig ◽  
David McCloskey ◽  
...  
Keyword(s):  
Thin Film ◽  
Transition Metal ◽  
2D Materials ◽  
Transition Metal Dichalcogenides ◽  
Metal Dichalcogenides ◽  
Group 10

Group-10 transition metal dichalcogenides (TMDs) are rising in prominence within the highly innovative field of 2D materials. While PtS2 has been investigated for potential electronic applications, due to its high...

scholarly journals Layered black phosphorus as a reducing agent – decoration with group 10 elements

RSC Advances ◽  
2020 ◽  
Vol 10 (60) ◽  
pp. 36452-36458
Author(s):  
Jan Plutnar ◽  
Zdeněk Sofer ◽  
Martin Pumera
Keyword(s):  
Transition Metals ◽  
Reducing Agent ◽  
Black Phosphorus ◽  
Group 10

Nanoparticles or films of group 10 transition metals or their phosphides can be produced on the surface of black phosphorus (BP) from the solutions of the respective M(ii) salts (M = Ni, Pd, Pt) utilizing BP as a reducing agent.

scholarly journals Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle

2019 ◽  
Vol 55 (75) ◽  
pp. 11279-11282 ◽  
Author(s):  
Kuiyuan Wang ◽  
Timothy J. Prior ◽  
Carl Redshaw
Keyword(s):  
Schiff Base ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Bimetallic Complexes

Homo-dinuclear Co or Zn complexes derived from a [2+2] Schiff-base macrocycle revealed near inactivity for the ring opening polymerization of δ-valerolactone and ε-caprolactone, whereas hetero-bimetallic complexes were efficient catalysts.

Sign in / Sign up

Export Citation Format

Share Document