scholarly journals Synthesis and structural characterization of arsinoamides – early transition metal (Zr and Hf) and main group metal (Al, In, Sn, and Pb) complexes

2019 ◽  
Vol 48 (40) ◽  
pp. 15207-15211
Author(s):  
Xiao Chen ◽  
Michael T. Gamer ◽  
Peter W. Roesky
Keyword(s):  
Transition Metal ◽  
Structural Characterization ◽  
Main Group ◽  
Early Transition Metal ◽  
Group Metal ◽  
Main Group Metal ◽  
Early Transition

The following complexes were synthesized: [(Mes2AsNPh)2MCl2(THF)], [(Mes2AsNPh)2M(NMe2)2] (M = Zr, Hf), [(Mes2AsNPh)AlCl2(THF)], [(Mes2AsNPh)InCl3][Li(THF)4], [(Mes2AsNPh)2E] (E = Sn, Pb).

Structural characterization of heteropolymeric iron and main group metal complexes

2012 ◽  
Vol 35 (1-2) ◽  
pp. 1-11
Author(s):  
Milan Melnik ◽  
Ondrej Sprušanský ◽  
Ján Garaj
Keyword(s):  
Metal Complexes ◽  
Structural Characterization ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal

Lewis-Base Adducts of Main Group Metal(I) Compounds. XI. Di-μ-iodo-bis(N,N,N′,N″,N″-pentamethyldiethylenetriamine-N,N′,N″-sodium)

1989 ◽  
Vol 42 (8) ◽  
pp. 1393 ◽  
Author(s):  
CL Raston ◽  
CR Whitaker ◽  
AH White
Keyword(s):  
Single Crystal ◽  
Structural Characterization ◽  
Structure Determination ◽  
Main Group ◽  
Lewis Base ◽  
Coordination Complex ◽  
X Ray ◽  
Group Metal ◽  
Main Group Metal

The synthesis and structural characterization of the 1:1 adduct of sodium(I) iodide and N,N,N′,N″,N″- pentamethyldiethylenetriamine (pmdeta), a novel coordination complex of sodium(I), is recorded. Single-crystal X-ray structure determination shows the compound to be a �,�′- diiodo-bridged dimer, with the tridentate base making up the five-coordinate environment of sodium: [( pmdeta )NaI2Na( pmdeta )]. Crystals are triclinic, P1, a 10.113(2),b 9.470(2), c 8.793(4) � , α 114.48(2), β 92.09(2), γ 96-65(1)°, Z= 1 dimer ; R was 0.037 for 1837 'observed' reflections.

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