The following complexes were synthesized: [(Mes2AsNPh)2MCl2(THF)], [(Mes2AsNPh)2M(NMe2)2] (M = Zr, Hf), [(Mes2AsNPh)AlCl2(THF)], [(Mes2AsNPh)InCl3][Li(THF)4], [(Mes2AsNPh)2E] (E = Sn, Pb).