MLi2Ti6O14 (M = Sr, Ba, and Pb): new cathode materials for magnesium–lithium hybrid batteries

2019 ◽  
Vol 48 (47) ◽  
pp. 17566-17571 ◽  
Author(s):  
Caixia Zhu ◽  
Yakun Tang ◽  
Lang Liu ◽  
Xiaohui Li ◽  
Yang Gao ◽  
...  

MLi2Ti6O14 (M = Sr, Ba, and Pb) were synthesized, for the first time, by a facile sol–gel method, followed by calcination and showed good electrochemical performance as cathodes for magnesium–lithium hybrid batteries.

RSC Advances ◽  
2015 ◽  
Vol 5 (92) ◽  
pp. 75333-75340 ◽  
Author(s):  
Qingqing Wang ◽  
Xiusheng Zhang ◽  
Yunlong Xu ◽  
Dong Liu ◽  
Hui Dong ◽  
...  

A series of Ni and F ion doped LiMn2O4 composite cathode materials are synthesized via a sol–gel method. LiNi0.03Mn1.97O3.95F0.05 exhibits an excellent electrochemical performance.


2013 ◽  
Vol 669 ◽  
pp. 311-315 ◽  
Author(s):  
Zhi Qiang Hu ◽  
Dong Xue Yang ◽  
Ke Jian Yin ◽  
Jing Xiao Liu ◽  
Fei Li ◽  
...  

LiFePO4/C cathode materials were synthesized by Sol-gel method under the same process conditions using different water-soluble lithium source (LiOH, Li2CO3, LiNO3). The phase of synthesized powders were characterized by XRD; and the electrochemical performance of the material was investigated by measurements of cyclic voltammetry, AC impedance measurements, charge and discharge. The results show that the synthesized LiFePO4/C using LiOH as the lithium source has high electrochemical reversibility and low internal impedance. The specific discharge capacity is 147.5mAh/g under the discharge at 0.2C rate. It also has high stability of cycle capacity, and almost no attenuation after 30 cycles. So it has the excellent electrochemical performance.


2010 ◽  
Vol 156-157 ◽  
pp. 1219-1222 ◽  
Author(s):  
Bo Quan Jiang ◽  
Shu Fen Hu ◽  
Min Wei Wang

The lithium vanadium phosphate (Li3V2(PO4)3 solid cathode materials were synthesized by microwave-heated sol-gel method using lithium hydroxide, ammonium metavanadate, phosphate and citric acid as starting materials. The test was conducted with orthogonal experiment method. The optimal conditions for (Li3V2(PO4)3 synthesis were determined to be microwave heating time of 10 min, microwave power of 700 W, Li/V molar ratio of 3.05:2.0 and pH value(gel solution) of 7.0. The synthesized (Li3V2(PO4)3 under the optimal conditions demonstrated perfect crystal growth and good electrochemical performance with initial charge/discharge specific capacity of 172.42 mAh·g-1/154.93 mAh·g-1 and discharge decay rate of 2.25 % after 50 cycles. The lithium ion diffusion coefficient was determined to be 1.434 ×10-8 cm2·s-1 by electrochemical impedance spectroscopy and mathematical models derived from simulative equivalent circuit.


2008 ◽  
Vol 178 (33-34) ◽  
pp. 1756-1761 ◽  
Author(s):  
L LIU ◽  
L JIAO ◽  
J SUN ◽  
M ZHAO ◽  
Y ZHANG ◽  
...  

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