Room-temperature liquid metal and alloy systems for energy storage applications

2019 ◽  
Vol 12 (9) ◽  
pp. 2605-2619 ◽  
Author(s):  
Xuelin Guo ◽  
Leyuan Zhang ◽  
Yu Ding ◽  
John B. Goodenough ◽  
Guihua Yu

Liquid metals and alloy systems that feature inherent deformability, high electronic conductivity, and superior electrochemical properties have enabled further development of next-generation energy storage devices.

Author(s):  
Ye Chen ◽  
Xinyu Yin ◽  
Shuyuan Lei ◽  
Xiaojing Dai ◽  
Xilian Xu ◽  
...  

MXene, a class of 2D transition metal carbide/nitride materials, has attracted widespread attention since its first discovery in 2011. Due to its high electronic conductivity, large specific surface area, good mechanical stability, and adjustable surface functional groups, MXene-based nanomaterials have shown great potential in energy storage devices. Meanwhile, zinc-based aqueous energy storage devices became a hotspot recently in energy storage field on account of their high security and low cost. In this review, the research progress on the preparation routes, preserving method, related structure and properties of MXene is first summarized. Followed by is an introduction of the recent state-of-the-art development of MXene-based electrodes for zinc-based aqueous energy storage devices, including zinc ion batteries (ZIBs), zinc-air batteries (ZABs), and zinc-halide batteries (ZHBs). Finally, the major bottleneck and perspectives for MXene-based nanomaterials in zinc-based aqueous energy storage devices are pointed out.


2020 ◽  
Vol 975 ◽  
pp. 127-132
Author(s):  
Chih Chieh Yang ◽  
Chia Hong Lee ◽  
Tseung Yuen Tseng

Nickel cobaltite has become a popular energy storage material in recent years for high performance energy storage devices because of its low lost, high electronic conductivity, high electrochemical activity and environmental benignity. Nickel cobaltite (NCO)/porous graphene nanosheets network (PG) composites were synthesized via the two-steps hydrothermal method to enhance electrochemical properties in this study. The NCO/PG composite electrode demonstrated high specific capacitance of 3965 F g-1 at the current density of 1 A g-1 compared with the value of NCO that capacitance is 644 F g-1, and it maintained the 72% of the original capacitance after 3,000 charge-discharge cycles. It showed the maximum energy density of 46.3 Wh kg-1 and maximum power density of 1450 W kg-1. The NCO/GO composite has high potential as a psudocapacitance material for energy storage devices.


2020 ◽  
Author(s):  
Ruhul Amin ◽  
Petla Ramesh Kumar ◽  
Ilias Belharouak

Carbon nanotubes (CNTs) are an extraordinary discovery in the area of science and technology. Engineering them properly holds the promise of opening new avenues for future development of many other materials for diverse applications. Carbon nanotubes have open structure and enriched chirality, which enable improvements the properties and performances of other materials when CNTs are incorporated in them. Energy storage systems have been using carbon nanotubes either as an additive to improve electronic conductivity of cathode materials or as an active anode component depending upon structural and morphological specifications. Furthermore, they have also been used directly as the electrode material in supercapacitors and fuel cells. Therefore, CNTs demand a huge importance due to their underlying properties and prospective applications in the energy storage research fields. There are different kinds of carbon nanotubes which have been successfully used in batteries, supercapacitors, fuel cells and other energy storage systems. This chapter focuses on the role of CNTs in the different energy storage and conversion systems and impact of their structure and morphology on the electrochemical performances and storage mechanisms.


Energies ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 8183
Author(s):  
Chenchen Ji ◽  
Haonan Cui ◽  
Hongyu Mi ◽  
Shengchun Yang

As newly emerged 2D layered transition metal carbides or carbonitrides, MXenes have attracted growing attention in energy conversion and storage applications due to their exceptional high electronic conductivity, ample functional groups (e.g., -OH, -F, -O), desirable hydrophilicity, and superior dispersibility in aqueous solutions. The significant advantages of MXenes enable them to be intriguing structural units to engineer advanced MXene-based nanocomposites for electrochemical storage devices with remarkable performances. Herein, this review summarizes the current advances of MXene-based materials for energy storage (e.g., supercapacitors, lithium ion batteries, and zinc ion storage devices), in which the fabrication routes and the special functions of MXenes for electrode materials, conductive matrix, surface modification, heteroatom doping, crumpling, and protective layer to prevent dendrite growth are highlighted. Additionally, given that MXene are versatile for self-assembling into specific configuration with geometric flexibility, great efforts about methodologies (e.g., vacuum filtration, mask-assisted filtration, screen printing, extrusion printing technique, and directly writing) of patterned MXene-based composite film or MXene-based conductive ink for fabricating more types of energy storage device were also discussed. Finally, the existing challenges and prospects of MXene-based materials and growing trend for further energy storage devices are also presented.


2020 ◽  
Vol 13 (10) ◽  
pp. 3527-3535 ◽  
Author(s):  
Nana Chang ◽  
Tianyu Li ◽  
Rui Li ◽  
Shengnan Wang ◽  
Yanbin Yin ◽  
...  

A frigostable aqueous hybrid electrolyte enabled by the solvation interaction of Zn2+–EG is proposed for low-temperature zinc-based energy storage devices.


2020 ◽  
Author(s):  
Yamin Zhang ◽  
Zhongpu Wang ◽  
Deping Li ◽  
Qing Sun ◽  
Kangrong Lai ◽  
...  

<p></p><p>Porous carbon has attracted extensive attentions as the electrode material for various energy storage devices considering its advantages like high theoretical capacitance/capacity, high conductivity, low cost and earth abundant inherence. However, there still exists some disadvantages limiting its further applications, such as the tedious fabrication process, limited metal-ion transport kinetics and undesired structure deformation at harsh electrochemical conditions. Herein, we report a facile strategy, with calcium gluconate firstly reported as the carbon source, to fabricate ultrathin porous carbon nanosheets. <a>The as-prepared Ca-900 electrode delivers excellent K-ion storage performance including high reversible capacity (430.7 mAh g<sup>-1</sup>), superior rate capability (154.8 mAh g<sup>-1</sup> at an ultrahigh current density of 5.0 A g<sup>-1</sup>) and ultra-stable long-term cycling stability (a high capacity retention ratio of ~81.2% after 4000 cycles at 1.0 A g<sup>-1</sup>). </a>Similarly, when being applied in Zn-ion capacitors, the Ca-900 electrode also exhibits an ultra-stable cycling performance with ~90.9% capacity retention after 4000 cycles at 1.0 A g<sup>-1</sup>, illuminating the applicable potentials. Moreover, the origin of the fast and smooth metal-ion storage is also revealed by carefully designed consecutive CV measurements. Overall, considering the facile preparation strategy, unique structure, application flexibility and in-depth mechanism investigations, this work will deepen the fundamental understandings and boost the commercialization of high-efficient energy storage devices like potassium-ion/sodium-ion batteries, zinc-ion batteries/capacitors and aluminum-ion batteries.</p><br><p></p>


Author(s):  
Dhanasekar Kesavan ◽  
Vimal Kumar Mariappan ◽  
Karthikeyan Krishnamoorthy ◽  
Sang-Jae Kim

In this study, we report a facile carbothermal method for the preparation of boron-oxy-carbide (BOC) nanostructures and explore their properties towards electrochemical energy storage devices.


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