Physical insights into mechanistic processes in organometallic chemistry: an introduction

2019 ◽  
Vol 220 ◽  
pp. 10-27 ◽  
Author(s):  
Robert H. Morris
Keyword(s):  
Transition Metal ◽  
Organometallic Chemistry ◽  
Metal Hydride ◽  
Late Transition Metal ◽  
Mechanistic Studies ◽  
Homogeneous Catalysts ◽  
Transition Metal Hydride ◽  
Late Transition

Mechanistic studies of late transition metal hydride homogeneous catalysts – 3d versus 4d metals.

Experimental and Computational Investigation of the Aerobic Oxidation of a Late Transition Metal-Hydride

2019 ◽  
Vol 141 (27) ◽  
pp. 10830-10843 ◽  
Author(s):  
Ashley M. Wright ◽  
Dale R. Pahls ◽  
J. Brannon Gary ◽  
Theresa Warner ◽  
Jacob Z. Williams ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydride ◽  
Aerobic Oxidation ◽  
Late Transition Metal ◽  
Computational Investigation ◽  
Transition Metal Hydride ◽  
Late Transition

Elucidating metal hydride reactivity using late transition metal boryl and borane hydrides: 2c–2e terminal hydride, 3c–2e bridging hydride, and 3c–4e bridging hydride

2018 ◽  
Vol 8 (13) ◽  
pp. 3395-3405 ◽  
Author(s):  
Yinwu Li ◽  
Jiahao Liu ◽  
Cheng Hou ◽  
Youxiang Shao ◽  
Ling-Bo Qu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydride ◽  
General Trend ◽  
Late Transition Metal ◽  
Late Transition

A general trend for the hydrogenation reactivity of metal hydride(s): 3c–4e bridging hydride > 2c–2e terminal hydride > 3c–2e bridging hydride.

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

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