Transition-metal-free carbonylation of aryl halides with arylboronic acids by utilizing stoichiometric CHCl3 as the carbon monoxide-precursor

2019 ◽  
Vol 21 (11) ◽  
pp. 2911-2915 ◽  
Author(s):  
Fangning Xu ◽  
Dan Li ◽  
Wei Han
Keyword(s):  
Carbon Monoxide ◽  
Transition Metal ◽  
Suzuki Coupling ◽  
Free Carbon ◽  
Aryl Halides ◽  
Metal Free ◽  
Arylboronic Acids ◽  
General Methodology

A transition-metal-free, carbon monoxide-free, and general methodology for carbonylative Suzuki coupling has been developed.

Transition-metal-free, ambient-pressure carbonylative cross-coupling reactions of aryl halides with potassium aryltrifluoroborates

2015 ◽  
Vol 51 (44) ◽  
pp. 9133-9136 ◽  
Author(s):  
Fengli Jin ◽  
Wei Han
Keyword(s):  
Transition Metal ◽  
Ambient Pressure ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Metal Free ◽  
General Methodology ◽  
Cross Coupling Reactions

A transition-metal-free, ambient-pressure, and general methodology for carbonylative Suzuki coupling has been developed.

Transition metal-free, iodide-mediated domino carbonylation–benzylation of benzyl chlorides with arylboronic acids under ambient pressure of carbon monoxide

2016 ◽  
Vol 18 (9) ◽  
pp. 2598-2603 ◽  
Author(s):  
Fengli Jin ◽  
Yanzhen Zhong ◽  
Xin Zhang ◽  
Huichun Zhang ◽  
Qian Zhao ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Transition Metal ◽  
Ambient Pressure ◽  
Metal Free ◽  
Arylboronic Acids ◽  
Benzyl Chlorides

Transition metal-free, ambient-pressure domino carbonylation–benzylation reactions by iodide catalysis have been developed.

Transition metal-free electrocatalytic halodeborylation of arylboronic acids with metal halides MX (X = I, Br) to synthesize aryl halides

2020 ◽  
Vol 7 (3) ◽  
pp. 590-595 ◽  
Author(s):  
Zhengjiang Fu ◽  
Guangguo Hao ◽  
Yaping Fu ◽  
Dongdong He ◽  
Xun Tuo ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Halide ◽  
Aryl Halides ◽  
Metal Halides ◽  
Metal Free ◽  
Arylboronic Acids ◽  
Halide Salts

An efficient and regioselective ipso-halogenation of diverse arylboronic acids with metal halide salts MX (X = I, Br) has been well established under electrochemical conditions.

Xanthene-9-carboxylic acid: A photo-activatable transition-metal-free carbon monoxide-releasing molecule with extraordinary long half-life

Nitric Oxide ◽  
2015 ◽  
Vol 47 ◽  
pp. S35 ◽  
Author(s):  
Lucie Muchová ◽  
Jana Jašprová ◽  
Tomáš Slanina ◽  
Peter Šebej ◽  
Petr Klán ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Carboxylic Acid ◽  
Transition Metal ◽  
Half Life ◽  
Free Carbon ◽  
Metal Free

scholarly journals Recent progress in application of nanocatalysts for carbonylative Suzuki cross-coupling reactions

RSC Advances ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 2112-2125
Author(s):  
Inci Söğütlü ◽  
Evan Abdulkarim Mahmood ◽  
Saeid Ahmadizadeh Shendy ◽  
Saeideh Ebrahimiasl ◽  
Esmail Vessally
Keyword(s):  
Carbon Monoxide ◽  
Recent Progress ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Arylboronic Acids ◽  
Cross Coupling Reactions ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds

Cross-coupling of aryl halides and arylboronic acids in the presence of carbon monoxide, also called carbonylative Suzuki coupling, to form two new carbon–carbon bonds in the production of synthetically and biologically important biaryl ketones, has been widely studied.

scholarly journals Transition-Metal-Free Cross-Coupling of Aryl Halides with Arylstannanes

2021 ◽  
Author(s):  
Qing He ◽  
Wenli Wang ◽  
Yong Liang ◽  
Zunting Zhang ◽  
Stanislaw F. Wnuk
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Aryl Halides ◽  
Metal Free

scholarly journals Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing

2020 ◽  
Vol 11 (17) ◽  
pp. 4499-4507 ◽  
Author(s):  
Jian Cheng ◽  
Bin Zheng ◽  
Sheng Cheng ◽  
Guoying Zhang ◽  
Jinming Hu
Keyword(s):  
Carbon Monoxide ◽  
Wound Healing ◽  
Photochemical Reactions ◽  
Free Carbon ◽  
Cutaneous Wound Healing ◽  
Cutaneous Wound ◽  
Metal Free ◽  
Improved Stability

Metal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.

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