Highly active and durable Pd nanocatalyst promoted by an oxygen-deficient terbium oxide (Tb4O7−x) support for hydrogenation and cross-coupling reactions

2019 ◽  
Vol 43 (23) ◽  
pp. 9210-9215
Author(s):  
Yi-Fan Jiang ◽  
Cheng-Zong Yuan ◽  
Tuck-Yun Cheang ◽  
An-Wu Xu

Oxygen-deficient Tb4O7−x as an effective promoter and support for Pd nanocatalysts holds great potential in hydrogenation and cross-coupling reactions.

2000 ◽  
Vol 65 (11) ◽  
pp. 1683-1697 ◽  
Author(s):  
Michal Hocek ◽  
Antonín Holý ◽  
Ivan Votruba ◽  
Hana Dvořáková

9-(2-Deoxy-β-D-erythro-pentofuranosyl)-6-(4-substituted phenyl)purines, 9-(5-deoxy-β-D-ribofuranosyl)-6-(4-substituted phenyl)purines and 9-(2,3-dihydroxypropyl)-6-(4-substituted phenyl)purines were prepared by the Suzuki-Miyaura cross-coupling reactions of the corresponding protected 9-substituted 6-chloropurines with substituted phenylboronic acids followed by MeONa mediated deprotection. In contrast to the highly active 6-phenylpurine ribonucleosides, the title compounds did not show any considerable cytostatic activity.


2020 ◽  
Vol 646 (15) ◽  
pp. 1336-1341 ◽  
Author(s):  
Xue-Fang Gong ◽  
Ling-Yan Zhang ◽  
Hui-Xin Zhang ◽  
Yu-Meng Cui ◽  
Fen-Chun Jin ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (25) ◽  
pp. 19630-19637 ◽  
Author(s):  
Shaheen M. Sarkar ◽  
Md. Lutfor Rahman ◽  
Mashitah Mohd Yusoff

Pyridinyl functionalized MCM-48-supported Pd-catalyst efficiently (0.013–0.025 mol%) promoted Heck, Suzuki and Sonogashira cross-coupling reactions. Moreover, the catalyst was reused five times without significant loss of its activity.


2018 ◽  
Vol 9 (46) ◽  
pp. 8673-8681 ◽  
Author(s):  
Petr Slavík ◽  
Dustin W. Kurka ◽  
David K. Smith

From waste to wealth – a self-assembled hydrogel remediates palladium from solution down to sub-ppm levels, and the resulting gel, which has embedded Pd nanoparticles, acts as a green and efficient catalyst for Suzuki–Miyaura cross-coupling reactions.


Polyhedron ◽  
2007 ◽  
Vol 26 (14) ◽  
pp. 3857-3864 ◽  
Author(s):  
Hong-Xing Wang ◽  
Hong-Fei Wu ◽  
Xiao-Li Yang ◽  
Nan Ma ◽  
Li Wan

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