Si nanoparticle clusters in hollow carbon capsules (SNC@C) as lithium battery anodes: toward high initial coulombic efficiency

Nanoscale ◽  
2019 ◽  
Vol 11 (28) ◽  
pp. 13650-13658 ◽  
Author(s):  
Tae Jin Kim ◽  
Jeong Hoon Yoon ◽  
Gi-Ra Yi ◽  
Pil J. Yoo

Clustered Si@C core–shell-structured particles are synthesized using an organic/inorganic emulsion polymerization process and utilized as a high performance anode material for Li-ion batteries with highly improved initial Coulombic efficiency.

Author(s):  
Ruoqian Jiang ◽  
Haocheng Yuan ◽  
Xianbin Wei ◽  
Haijun Wang ◽  
Hee-Jae Shin ◽  
...  

Silicon (Si) is a promising anode for Lithum-ion batteries (LIBs) due to high theoretical capacity (4200 mAh g-1). However, low initial coulombic efficiency (ICE) and utilization efficiency due to volume...


ChemSusChem ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 3377-3382 ◽  
Author(s):  
Rusheng Fu ◽  
Yongkang Wu ◽  
Chongzhao Fan ◽  
Zuxin Long ◽  
Guangjie Shao ◽  
...  

2017 ◽  
Vol 5 (19) ◽  
pp. 9262-9271 ◽  
Author(s):  
Tony Jaumann ◽  
Maik Gerwig ◽  
Juan Balach ◽  
Steffen Oswald ◽  
Erica Brendler ◽  
...  

A scalable synthesis for a large amount of silicon nanoparticles (<10 nm) embedded within hollow carbon spheres as a high-performance anode for Li-ion batteries.


2017 ◽  
Vol 9 (16) ◽  
pp. 14180-14186 ◽  
Author(s):  
Yufen Yang ◽  
Song Jin ◽  
Zhen Zhang ◽  
Zhenzhen Du ◽  
Huarong Liu ◽  
...  

2013 ◽  
Vol 5 (8) ◽  
pp. 3449-3455 ◽  
Author(s):  
Min Zhou ◽  
Tingwei Cai ◽  
Fan Pu ◽  
Hao Chen ◽  
Zhao Wang ◽  
...  

2015 ◽  
Vol 1092-1093 ◽  
pp. 185-190 ◽  
Author(s):  
Jing Wang ◽  
Mei Juan Zhou ◽  
Feng Wu ◽  
Shi Chen

Dopamine was used as the carbon precursor to prepare SiO/C composite. Dopamine achieved self-polymerization and covered on the surface of the SiO particles in Tris-buffer, and the SiO/C composites were gained after heat-treating in the tube furnace under Argon. X-ray diffraction ( XRD ) , scanning electron microscope ( SEM ) were used to determine the phases obtained and to observe the morphologies of the composite. The galvanostatic discharge/charge test was carried out to characterize the electrochemical properties of the composite. When the sample of the mixed SiO and dopamine at a weight ratio of 1 : 3, the composite showed the best cycle ability with the discharge capacity of 1362 mAh g−1 in the first cycle, and the initial coulombic efficiency is 55.6%, after 50 cycles, the discharge capacity is 442 mAh g−1. The improved stability of the composite is attributed to carbon-coating forming during heat-treatment process.


2016 ◽  
Vol 11 (8) ◽  
pp. 1205-1209 ◽  
Author(s):  
Quan Xu ◽  
Jin-Yi Li ◽  
Ya-Xia Yin ◽  
Yi-Ming Kong ◽  
Yu-Guo Guo ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 7959-7963 ◽  
Author(s):  
Shengbin Wang ◽  
Yalan Xing ◽  
Changlei Xiao ◽  
Xin Wei ◽  
Huaizhe Xu ◽  
...  

A novel N-doped hollow hierarchical carbon-shell/carbon-nanorod arrays (N-HPC) have been constructed. When evaluated as electrode material for LIBs and supercapacitors, the N-HPC manifests outstanding rate capability and excellent cycling performance.


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